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  • 1
    Publication Date: 2017-10-06
    Description: Fumarolic alteration crusts and efflorescences have been sampled at the Sousaki solfataric field. Samples have been analysed for mineralogical (XRD) and chemical composition (HNO3 digestion and leaching with distilled water). Results show that mineralogical and chemical compositions (major, minor and trace metals) are controlled by microenvironmental conditions. The sample collected in the anoxic part of a cave is composed almost exclusively by native sulfur. The samples collected in the oxidizing part of the cave and outside in relatively sheltered position are mainly composed by very soluble sulfates. Chemical composition evidence strong enrichments in Al, Ca, Cr, Fe, Mg and Ni which are present in highly soluble form and derive from the fumarolic alteration of the outcropping rocks (Marls and peridotites). One sample collected outside the cave, well exposed to atmospheric agents, is composed almost exclusively of gypsum and the chemical composition reveals, with respect to the previous samples, a relative enrichment of elements (Ba, Ca, K, Pb and Sr) forming less soluble sulfates. The presence of toxic metals like Al, Cr and Ni in high concentrations and highly soluble form evidences the potential impact of the fumarolic activity on the local environment.
    Description: Published
    Description: Myconos, Greece
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Hydrothermal alteration products ; sulfates ; toxic metals ; elements’ mobility ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 2
    Publication Date: 2023-11-21
    Description: Crystallization experiments on two pantellerites from Pantelleria, Italy, provide new evidence for the relationships between mineral phases in pantelleritic rocks aswell as the influence of temperature and redox conditions on mineral assemblages. Experiments were performed at 1 kbar with temperature ranging between 750–900°C, and fluid saturation conditionswith XH2O (=H2O/H2O+CO2) between 0 and 1. Redox conditionswere fixed at, or slightly below, the FMQbuffer. Results showthat at temperature of 900 °C pantelleriticmagmas arewell above the liquidus regardless their water content; we also observed a decrease in liquidus temperature (800°C) with increasingly reducing conditions. Mineral assemblages of the natural rocks have been successfully reproduced, particularly the relationship between fayalite and aenigmatite, which appear to be strongly controlled by melt peralkalinity, temperature and redox conditions. This is the first time that fayalitic olivine have been synthetized in experimental studies on pantellerites, which was found to be stable only for temperatures ≥750°C while amphibole can be stable at temperatures as high as 800°C at high fF2. Experimental results have been compared with the composition of mineral phases as well as with the results obtained from mineral equilibrium, geothermometry, and oxygen barometry studies on pantelleritic lava and tuffs from Pantelleria (Italy), Eburru (Kenya) and Menengai (Kenya). Petrological characteristics appear similar at different locations worldwide, with typical assemblages of anorthoclase and sodian clinopyroxene with variable fayalite, aenigmatite, Fe-Ti oxides and amphibole.
    Description: Published
    Description: 105793
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Pantellerite, Mineral Equilibria, Experimental Petrolog, Peralkaline magmas ; 03.01. General
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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