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  • 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects  (26)
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  • 1
    Publication Date: 2017-04-04
    Description: The chemical and isotopic compositions of the precipitation at Stromboli Island, Italy, were investigated between October 2003 and October 2005. We employed a rain gauge network designed to cover the range in exposures and elevations of the volcanic edifice. The hydrogen and oxygen isotopic ratios vary greatly on a seasonal basis and correlate with air temperature. Deuterium excess values show a positive correlation with altitude. No direct contribution of volcanogenic H or O is evident in the isotopic composition of the rainwater. The chemical composition of the rainwater is principally controlled by the sea aerosol contribution at the coastal sites, whereas it is significantly influenced by volcanic activity near the summit vents. Interaction with volcanic acid gases is indicated by the pH, which is usually 1–2 units lower near the craters than at the coastal sites. The S/Cl, Cl/F, and S/F molar ratios in rainwater 1.5 km from the craters are consistent with those measured in the volcanic plume using other methods (diffusive tubes and Fourier transform infrared spectroscopy). Rising of undegassed magmas changes these molar ratios because of the differential degassing of sulphur, chlorine, and fluorine from the magma. We therefore propose that the chemical composition of precipitation, within 1.5 km of the craters, provides additional information that is useful for monitoring volcanic activity at Stromboli Island. Moreover, this paper presents estimates of the fluxes of F, Cl, S, Na, K, Ca, and Mg to the soil that could be useful for geochemical studies on groundwater.
    Description: Published
    Description: Q07006
    Description: JCR Journal
    Description: reserved
    Keywords: rainwater ; isotopic composition ; plume ; volcanic gases ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Volcanoes contribute to atmospheric pollution by increasing the amount of reactive and greenhouse gases and aerosols, making volcanic emissions one of the major natural sources of several trace elements to the atmosphere. In particular, Mt. Etna is considered to be, on the long-term average, the major atmospheric point source of many environmental harmful compounds. Their emission occurs in the form of gases, aerosols or particulate, both through continuous passive degassing from open-conduit activity and through sporadic paroxysmal eruptive activity. To estimate the environmental impact of magma-derived trace metals and their depositions processes, five bulk collectors have been deployed at various altitudes on the upper flanks around the summit craters of the volcano. Samples were collected every second week for a period of one year and analyzed for the main chemical-physical parameters (electric conductivity and pH) and for major and trace elements concentrations. The first data obtained clearly show that the volcanic contribution is always prevailing in the sampling site closest to the summit craters (∼1.5 km). In the distal sites (5.5-10 km from the summit) downwind of the summit craters, the volcanic contribution is also detectable but often overwhelmed by anthropogenic or other natural (seawater spray, geogenic dust) contributions. Volcanic contribution may derive from both dry and wet deposition of gases and aerosols from the volcanic plume, but sometimes also from leaching of freshly emitted volcanic ashes. In fact, in our background site (7.5 km in the upwind direction,) volcanic contribution has been detected only following an ash deposition event. Fluorine, S and Cl, are the major elements that prevailingly characterize the volcanic contribution in bulk deposition on Mt. Etna, but high concentrations of many trace elements are also detected in the studied samples. In particular, Si, Al, Fe, Ti, Cu, As, Rb, Pb, Tl, Cd, Cr, U and Ag display, in the site most exposed to the volcanic emissions, median concentration values about two orders of magnitude higher than those measured in our background site. Furthermore some of the analysed elements display very high enrichment values with respect to the average crust and, in the closest site to the summit craters, also deposition values higher than those measured in polluted urban or industrial sites.
    Description: Unpublished
    Description: Athens, Greece
    Description: 4.5. Degassamento naturale
    Description: open
    Keywords: Mt. Etna ; trace elements ; rainwater ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 3
    Publication Date: 2017-04-04
    Description: Significant changes in both the chemistry of coastal thermal waters and the soil CO2 and Rn emissions in the crater area were recorded at Stromboli prior to the eruption that began on 28 December 2002. The dissolved CO2 contents and the d13C and 3He/4He values were elevated in the thermal aquifer from July 2002. Synchronous variations in the same isotope ratios were recorded in the summit fumarolic gases, with both 3He/4He and d13C values of gases released from a fumarole in the summit area increasing between May and November 2002. These variations are indicative of early degassing of a new gas-rich magma batch with a 13C- and 3He-rich signature. This magma recharge probably fed the intense Strombolian activity recorded during that period. The eruption began with a major explosion that produced a glowing avalanche, immediately followed by a fluid lava overflow from the NE crater and subsequent lava effusion from vents opened in the Sciara del Fuoco depression. Sharp increases in CO2 soil flux and Rn emissions— to values never observed previously—were recorded in the summit crater area 10 d before the eruption onset. These CO2 and Rn anomalies are indicative of a high gas-driven magma supply rate and gas overpressure within the conduit. The sudden depressurization of the magma filling the upper conduit probably caused the major explosion that occurred on 28 December, which heralded the effusive phase. These data demonstrate the importance of collecting a wide spectrum of geochemical data from different geological sites when monitoring a volcano.
    Description: Submitted
    Description: 4.5. Degassamento naturale
    Description: reserved
    Keywords: Stromboli ; geohcemical monitoring ; carbon and helium isotopes ; CO2 and Rn soil emissions ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 4
    Publication Date: 2017-04-04
    Description: Volcanic activity is the main natural sources of sulphur dioxide (SO2) to the atmosphere. Although total anthropogenic sources are overwhelming greater, volcanoes like Mt. Etna and many others are considered to be among the biggest point sources of SO2 also during intereruptive periods. Apart from being one of the most impressive geodynamic expressions, volcanoes are also an important tourist attraction. During the summer season the number of tourists visiting the summit craters each day is on average many tens at Stromboli, hundreds at Vulcano and thousands at Mt. Etna. Of course touristic exploitation of active volcanic areas cannot exempt from warranting a reasonable security to the visiting persons. But while many risks in these areas have been since long time considered, gas hazard, a very subtle risk, is often disregarded. For healthy persons, about 1000 µg m-3 of sulphur dioxide is sensed by smell, 2000 to 4000 µg m-3 cause eye, nose and throat irritation, and 10,000 to 15,000 µg m-3 cause respiratory failure. For individuals with bronchial asthma or lung diseases, exposure to much lower doses could be fatal. Generally, a 700 µg m-3 level is considered to be a safe limit for such persons. The atmospheric concentrations of naturally emitted SO2 were measured at three volcanoes of southern Italy (Mt. Etna, Vulcano and Stromboli). Measurements were made with a network of passive samplers positioned at about 1.5 m above the ground, which gave time-integrated values for periods from few days to 1 month. Samplers were placed in zones of the volcanoes with high tourist frequentation. Measured concentrations reach values as high as 2700, 2400 and 10,000 µg m-3 for Etna, Vulcano and Stromboli respectively. Such values are absolutely dangerous to people affected by bronchial asthma or lung diseases. But considering that these are average values over periods from few days up to one month, SO2 concentrations could reach much higher peak values that could be dangerous also to healthy people. The present study evidences a peculiar volcanic risk connected to the touristic exploitation of active volcanic areas. Such risk is particularly enhanced at Mt.Etna where elderly and not perfectly healthy people can easily reach, with cableway and off-road vehicles, areas with dangerous SO2 concentrations.
    Description: Published
    Description: Bari, Italy
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: volcanic degassing ; sulphur dioxide ; passive samplers ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 5
    Publication Date: 2017-04-04
    Description: Methane plays an important role in the Earth’s atmospheric chemistry and radiative balance being the second most important greenhouse gas after carbon dioxide. Methane is released to the atmosphere by a wide number of sources, both natural and anthropogenic, with the latter being twice as large as the former (IPCC, 2007). It has recently been established that significant amounts of geological methane, produced within the Earth’s crust, are currently released naturally into the atmosphere (Etiope, 2004). Active or recent volcanic/geothermal areas represent one of these sources of geological methane. But due to the fact that methane flux measurements are laboratory intensive, very few data have been collected until now and the contribution of this source has been generally indirectly estimated (Etiope et al., 2007). The Greek territory is geodynamically very active and has many volcanic and geothermal areas. Here we report on methane flux measurements made at two volcanic/geothermal systems along the South Aegean volcanic arc: Sousaki and Nisyros. The former is an extinct volcanic area of Plio-Pleistocene age hosting nowadays a low enthalpy geothermal field. The latter is a currently quiescent active volcanic system with strong fumarolic activity due to the presence of a high enthalpy geothermal system. Both systems have gas manifestations that emit significant amounts of hydrothermal methane and display important diffuse carbon dioxide emissions from the soils. New data on methane isotopic composition and higher hydrocarbon contents point to an abiogenic origin of the hydrothermal methane in the studied systems. Measured methane flux values range from –48 to 29,000 (38 sites) and from –20 to 1100 mg/mˆ2/d (35 sites) at Sousaki and Nisyros respectively. At Sousaki measurement sites covered almost all the degassing area and the diffuse methane output can be estimated in about 20 t/a from a surface of about 10,000 mˆ2. At Nisyros measurements covered the Stephanos and Kaminakia areas, which represent only a part of the entire degassing area. The two areas show very different methane degassing pattern with latter showing much higher flux values. Methane output can be estimated in about 0.25 t/a from an area of about 30,000 mˆ2 at Stephanos and about 1 t/a from an area of about 20,000 mˆ2 at Kaminakia. The total output from the entire geothermal system of Nisyros probably should not exceed 2 t/a.
    Description: Published
    Description: Vienna, Austria
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: methane output ; diffuse degassing ; volcanic/hydrothermal systems ; Greece ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 6
    Publication Date: 2017-04-04
    Description: A biomonitoring survey, above tree line level, using two endemic species (Senecio aethnensis and Rumex aethnensis) was performed on Mt. Etna, in order to evaluate the dispersion and the impact of volcanic atmospheric emissions. Samples of leaves were collected in summer 2008 from 30 sites in the upper part of the volcano (1500- 3000 m a.s.l). Acid digestion of samples was carried out with a microwave oven, and 44 elements were analyzed by using plasma spectrometry (ICP-MS and ICP-OES). The highest concentrations of all investigated elements were found in the samples collected closest to the degassing craters, and in the downwind sector, confirming that the eastern flank of Mt. Etna is the most impacted by volcanic emissions. Leaves collected along two radial transects from the active vents on the eastern flank, highlight that the levels of metals decrease one or two orders of magnitude with increasing distance from the source. This variability is higher for volatile elements (As, Bi, Cd, Cs, Pb, Sb, Tl) than for more refractory elements (Al, Ba, Sc, Si, Sr, Th, U). The two different species of plants do not show significant differences in the bioaccumulation of most of the analyzed elements, except for lanthanides, which are systematically enriched in Rumex leaves. The high concentrations of many toxic elements in the leaves allow us to consider these plants as highly tolerant species to the volcanic emissions, and suitable for biomonitoring researches in the Mt. Etna area.
    Description: Published
    Description: Vienna, Austria
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Mt. Etna ; biomonitoring ; Trace elements ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 7
    Publication Date: 2017-04-04
    Description: From December 2002 to July 2003, Stromboli volcano was characterized by a new effusive stage of eruption after a period of extraordinary strombolian activity. Signals recorded in two continuous monitoring stations during the eruption, which have already been presented in very recent papers, evidenced anomalies in the CO2 flux just before the onset of the eruption. A more detailed analysis carried out on the data subset acquired during the eruption, integrated by daily field observations of the scientific personnel working at the volcanological observatory in Stromboli, showed that CO2 flux and soil temperature are strictly related to volcanic events. Furthermore, the relative minima and maxima of the two parameters showed a strong correlation with wind speed and direction. This fact was especially true at the summit station, whereas at the coastal sites seasonal and meteorological effects masked the volcanic signal. The analysis of the wind data, particularly the relationships between wind speed and direction, air and soil temperature, and local circulation of atmospheric air masses revealed that during the eruption, in the summit area of Stromboli air movements were not only related to atmospheric circulation but were also significantly affected, and in certain cases caused, by volcanic activity. This conclusion was reached by observing several anomalies, such as the discrepancies in the wind direction between the two stations, higher air temperatures at the summit site, and inversion of direction for wind before and after the reopening of the conduit in a major explosion on 5 April 2003. The relationships found between volcanic activity, soil temperatures, CO2 fluxes, and wind speed and direction indicate that soil temperature measurements, in an open conduit volcano such as in this case, could be used to monitor the level of volcanic activity, along with CO2 flux. Furthermore, the possible volcanic origin of a peculiar type of air circulation identified in the summit area of Stromboli suggests that the separation between volcanic and atmospheric signals might not be obvious, requiring monitoring over a wide area, rather than a single location.
    Description: Published
    Description: Q12001
    Description: partially_open
    Keywords: carbon dioxide flux ; continuous monitoring ; soil temperature ; wind ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 2636190 bytes
    Format: 503 bytes
    Format: application/pdf
    Format: text/html
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  • 8
    Publication Date: 2017-04-04
    Description: Volcanic and geothermal areas are one of the major natural sources of H2S to the atmosphere. Its environmental impact is often the main cause of the opposition to the development of geothermal energy exploitation programs. In this paper we analyze the air concentrations and dispersion pattern of naturally emitted H2S at the geothermal area of Sousaki (Corinthia, Greece). Measurements, made with a network of passive samplers, evidence a rapid decrease of concentration values away from the emission points. The fact that the decrease is more pronounced in the summer with respect to the winter indicates that it is not only due to a dilution effect, but also to redox reactions favoured by higher temperatures and intense sunlight typical of the summer period.
    Description: Published
    Description: 1723-1728
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Hydrogen sulphide ; Environmental impact of volcanic activity ; Gas hazard ; Passive samplers ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2017-04-04
    Description: Chemical and isotopic analyses of the main gas manifestations of the island of Pantelleria (Italy) were used to gain insight on the origin of the released methane. Results indicate that the most probable origin is through abiogenic reactions within the hydrothermal system. Methane and CO2 flux measurements from the soils were made with the accumulation chamber method in an area of about 0.015 km2 within the main fumarolic area of the island (Favara Grande). The 23 measurements range from –34 to 3550 mg m-2 d-1 for CH4 and from 0.6 to 379 g m-2 d-1 for CO2. The relationships between CH4 and CO2 fluxes and the CH4/CO2 ratios in the gases collected between 25 and 100 cm depth provide evidence for methanotrophic processes within the soils. Methane output for the surveyed area was calculated in 2.5 t a-1 and extrapolated to about 5-10 t a-1 for the entire volcanic/hydrothermal system of the island. Previous higher estimates of the CH4 output at Pantelleria (Etiope et al., 2007 - J. Volcanol. Geotherm. Res., 165, 76 – 86) were based on soil CO2 output and CH4/CO2 ratios in fumarolic gases; the present work provides the first direct CH4 flux data and it suggests that methanotrophic activity in the soil could be substantial in reducing the CH4 emission to the atmosphere.
    Description: Published
    Description: 147-157
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: hydrothermal systems ; gas geochemistry ; isotope composition ; methane output ; methanotrophic consumption ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2017-04-04
    Description: Volcanic and geothermal areas are one of the major natural sources of environmentally relevant gases to the atmosphere. Hydrogen sulphide (H2S) is a toxic gas, which is rather always present in geothermal fluids. Like carbon dioxide, being a gas that is denser than atmospheric air, it can accumulate in topographic depressions and enclosures sometimes reaching concentrations (500-1000 ppm) lethal to humans and animals. It has a characteristic odor of rotten eggs to which the human smell is very sensible (odor threshold as low as 10 ppb for very sensible persons). The south Aegean volcanic arc, which is related to the subduction of the African plate beneath the Eurasian plate, comprises many active or extinct volcanic centres. Most of them are characterised by the presence of fumarolic areas. The peculiarity and beauty of such manifestations attracts each year thousands of tourists many of which go very close to the emission vents. In the present study we measured the atmospheric concentrations and dispersion pattern of naturally emitted H2S at four fumarolic areas (Thiochoma – Sousaki, Fyriplaka – Milos. Nea Kameni – Santorini, Lakki plain – Nisyros). Measurements were made with a network of passive samplers positioned at about 1.5 m above the ground, which gave time-integrated values for periods ranging from days to weeks. Values ranged from 0.1 to 2050 ppb at Sousaki, from 0.8 to 33.8 ppb for Milos, from 0.1 to 5.1 ppb for Santorini and from 1.6 to 1240 ppb for Nisyros. At all the fumatolic areas concentrations decreased exponentially with increasing distances from the source. The highest values were recorded at distances of about 5-20 m from the fumarolic vents. The striking difference between the highest values measured at Sousaki and Nisyros with respect to Milos and Santorini depends on two main factors. The first factor is a higher H2S emission rate at the former two sites (stronger total gas emission and higher H2S concentrations). The second factor is the geomorphology of the same two sites that limits the gas exchange with the open atmosphere. In fact, while the fumarolic area of Sousaki is in a narrow ravine and that of Nisyros is within the calderic depression of the island, the fumarolic areas of Milos and Santorini are well exposed to free atmospheric circulation. Nevertheless also the highest measured concentrations, although disconfortable, does not have adverse effects on human health.
    Description: Published
    Description: Bari, Italy
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: Volcanic degassing ; Hydrogen sulphide ; passive samplers ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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