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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 23 (1985), S. 1573-1584 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The optical constants n and k of polyacrylonitrile (PAN) were determined in the infrared region 3100-700 cm-1 by using theoretical calculations and experimental reflectance spectra. Tests of the validity of the results obtained showed excellent agreement between the measured and the predicted k values. One k value was determined experimentally (k = 0.6155 at V = 2285 cm-1) and showed excellent agreement with that calculated theoretically (k = 0.6153). The p-polarized light was found to be more sensitive than the s-polarized light to the absorbance of PAN films at 77° incidence angle. This sensitivity increased rapidly with p-polarized light for film less than 0.5 μm thick. From the optical constants obtained for p-polarized light at 77° angle of incidence, the sensitivity of the infrared reflection-absorbance (IR-RA) measurements to changes in the functional group concentrations in PAN films was determined for film thicknesses in the region 0.01-10.0 μm. The IR-RA measurements of the —C≡N group and the skeletal mode were for a PAN film thickness of about 0.1 μm.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2022-05-25
    Description: Assessing the skill of the Atlantic meridional overturning circulation (AMOC) in decadal hindcasts (i.e. retrospective predictions) is hampered by a lack of obser- vations for verification. Models are therefore needed to reconstruct the historical AMOC variability. Here we show that ten recent oceanic syntheses provide a common signal of AMOC variability at 45°N, with an increase from the 1960s to the mid-1990s and a decrease thereafter although they disagree on the exact magnitude. This signal corre- lates with observed key processes such as the North Atlantic Oscillation, sub-polar gyre strength, Atlantic sea surface temperature dipole, and Labrador Sea convection that are thought to be related to the AMOC. Furthermore, we find potential predictability of the mid-latitude AMOC for the first 3–6 year means when we validate decadal hindcasts for the past 50 years against the multi-model signal. However, this predictability is not found in models driven only by external radiative changes, demonstrating the need for initialization of decadal climate predictions.
    Description: Published
    Description: 775-785
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: restricted
    Keywords: Decadal prediction 􏰁 Atlantic MOC 􏰁 Predictability 􏰁 Multi-model comparison ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models ; 03. Hydrosphere::03.03. Physical::03.03.03. Interannual-to-decadal ocean variability
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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