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  • 1
    Electronic Resource
    Electronic Resource
    Fe(III) complexes of d-glucose and d-fructose (1994)
    Springer
    BioMetals 7 (1994), S. 25-29 
    Details
    ISSN: 1572-8773
    Keywords: complexes ; Fe(III) ; fructose ; glucose
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Fe(III)-saccharide complexes of d-glucose and d-fructose have been synthesized from methanol using stoichiometric quantities of sodium salts of the corresponding saccharides. Both the compounds were isolated in the solid state and characterized by various analytical, spectroscopic, magnetic and cyclic voltammetric methods. Both the complexes were found to be stable, in solution, in the pH range 2.5–12.0.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00205190
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  • 2
    Electronic Resource
    Electronic Resource
    Transition metal-saccharide chemistry: d-glucose complexes of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) (1995)
    Springer
    BioMetals 8 (1995), S. 19-24 
    Details
    ISSN: 1572-8773
    Keywords: Co(II) ; complexes ; Cu(II) ; glucose ; Mn(II) ; Ni(II) ; saccharide ; transition metal ; Zn(II)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Metal complexes of d-glucose (d-Glc) from large cation containing dibromo-dichloro salts of dipositive metals [NEt4]2[MBr2Cl2] (M = Mn, Co, Ni, Cu and Zn) and the disodium salt of glucose were synthesized from a MeOH:MeCN mixture. The complexes were characterized by UV-vis absorption, circular dichroism, IR and proton magnetic resonance spectroscopies, and by elemental analysis, and were found to be Na[M(d-Glc)(OMe)Cl]. Cyclic voltammetric studies of these complexes, in the acidic to neutral pH range, indicated no dissociation, even in highly acidic conditions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00156153
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    Paper (German National Licenses)
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