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  • 1
    Electronic Resource
    Electronic Resource
    Electrochemical oxidative ring opening of 1-methylcyclobutanol (1996)
    Springer
    Russian chemical bulletin 45 (1996), S. 1246-1248 
    Details
    ISSN: 1573-9171
    Keywords: 1-methylcyclobutanol ; manganese(III) acetate ; electrochemical oxidation ; pentane-2-one ; 5-chloropentane-2-one ; β-cleavage
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The manganese(III) acetate-mediated electrooxidative ring opening of 1-methylcyclobutanol (1) in acetic acid affords pentane-2-one (2) as the major product. The reaction of 1-methylcyclobutanol with Mn(OAc)3-LiCl gives 5-chloropentane-2-one (4.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01431635
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  • 2
    Electronic Resource
    Electronic Resource
    Oxidation of 1-methylcyclobutanol by Pb(IV) and Mn(III) compounds (1992)
    Springer
    Russian chemical bulletin 41 (1992), S. 2189-2192 
    Details
    ISSN: 1573-9171
    Keywords: oxidation ; 1-methylcyclobutanol ; lead tetraacetate ; manganese triacetate ; β-cleavage
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The main product of the reaction of 1-methylcyclobutanol with Pb(OAc)4 in benzene is 1-phenyl-4-pentanone; the use of Mn(OAc)3 in acetic acid gives a mixture of 2,9-decanedione and methyl propyl ketone; 1-(chloro-, bromo-, thiocyano-, or cyano)-4-pentanone is formed in the presence of the systems Pb(OAc)4-metal halide or Mn(OAc)3-metal halide.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01150744
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  • 3
    Electronic Resource
    Electronic Resource
    The effect of electrolysis conditions on the oxidation of styrene in methanol (1994)
    Springer
    Russian chemical bulletin 43 (1994), S. 1536-1540 
    Details
    ISSN: 1573-9171
    Keywords: styrene, anodic oxidation, electrochemical cleavage of carbon-carbonπ and σ-bonds ; (1,2-dimethoxyethyl)benzene ; benzaldehyde dimethylacetal ; (1,1,2-trimethoxyethyl)- and (l,2,2-trimethoxyethyl)benzenes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Anodic oxidation of styrene (1) in methanol and the effect of the anion of the supporting electrolyte and of the anode material on this process have been studied. The most efficient conversion of1 into (1,2-dimethoxyethyl)benzene (2) occurs when the electrolysis is carried out with a platinum anode and with potassium fluoride or tetrabutylammonium tetrafluoroborate as the supporting electrolyte. Cleavage of the C-C σ bond in2 to give benzaldehyde dimethylacetal (3) is the most efficient at a graphite anode in the presence of sodium tosylate.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00697143
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