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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 8 (1964), S. 2067-2093 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Undrawn nylon was found to be susceptible within a few days to degradation in wet or humid conditions at temperatures between 50 and 90°C. Model N-substituted amides, although not affected by these conditions, were attacked by hydrogen peroxide solutions. The degradation proceeded principally by rupture of the bond between the nitrogen of the amide and the carbon of its α-methylene group, consequent upon oxidation at this carbon. Unsubstituted primary amide, carboxyl, and aldehyde endgroups were formed, together with ammonia by hydrolysis of the oxidized amide. The bond between the α and β carbons of an N-methylene chain also suffered breakage, giving formic acid and carbon dioxide. The former could also arise by rupture of any initially produced N-formyl or N-formoyl amides. The appearance of lactic acid from butylacetamide showed that oxidation could proceed along the N-alkyl chain. Fragments of suitable size broken from the main chain of nylon became water-soluble and relatively stable to further attack by air or oxygen. These pieces essentially retained the nylon structure, but possessed two carboxylic ends and an average molecular weight of less than 600. A maximum oxygen uptake of about 30 moles per mole of original amide was calculated, corresponding to complete conversion into these soluble fragments. Significant degradation did not occur for many months at 60°C. in dry conditions or in solutions of 8-hydroxyquinoline, a process which has been patented. The latter was considered to function by chelating heavy metals into an inactive form and inhibiting peroxide formation.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 24 (1979), S. 89-103 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Pneumacel, a new kind of resilient closed-cell foam, has characteristics especially useful for firm cushioning materials. A fluorocarbon inflatant in addition to air present in the closed cells provides a mechanism for recovery from long-term loading for nonelastomeric polymer foams such as poly(ethylene terephthalate). The basic structural features characterizing pneumacel contribute to its performance as a resilient foam. Important principles in selecting the optimum combination of polymer and inflatant are described, as well as the process for making pneumatic cellular products. Development work on applications of pneumacel fibers has led to its utilization in cushions for under carpets, padding for use over springs in mattresses, automobile seats, and furniture. Properties of the assemblies of fibers for such uses are described.
    Additional Material: 7 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 8 (1964), S. 257-282 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Yarns of nylon and polyethylene-terephthalate were subjected to snatch loadings of quarter period 5 × 10-2 sec. and stress amplitudes up to break, by impacting at several known levels of energy. Force developed was measured as a function of time by means of a capacitance gauge, and the extension by photographing the movement of a small torch attached to the yarn. The equivalent linear modulus, calculated from the period of longitudinal oscillation at low energy input, agreed broadly with the initial modulus of the dynamic load-extension curves. In repeated impact at a given energy level, the total deformation increased logarithmically with time, but the extension attributable to individual impacts decreased. There was a corresponding progressive increase in dynamic tension, but the breaking tension was not apparently affected either by the number of previous impacts or by the energy level. Breaking loads of a nylon yarn, reached in 10-2, 10, and 103 sec., were compared at temperatures from 20 to 250°C. Tenacity decreased with temperature at a rate depending on the time to break, but the tenacity at a temperature of about 240°C. was substantially independent of rate of loading. Strain-time relationships, obtained at various temperatures using a photoelectric technique, were compared and analysed.
    Additional Material: 15 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 13 (1978), S. 547-548 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mass spectrometric studies have been made of the [(C7H8)Cr]+ ions generated from (η6-PhCH3)Cr(CO)3 and (η6-c-C7H8)Cr(CO)3. Fragmentation behaviour and appearance potential measurements have been used to show that the ions from the two precursors do not achieve a common structure. [(C8H10)Cr]+ generated from (η6-PhEt)Cr(CO)3 and (η6-c-C7H7Me)Cr(CO)3 behave similarly. A study of the α-d3 toluene complex suggests the structure [CH3C6H4-CrH]+ is appropriate for [C7H8Cr]+ ions generated from (η6-PhMe)Cr(CO)3 and decomposing to [CrH]+.
    Additional Material: 1 Tab.
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  • 5
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: First field free region metastable fragmentations of (η6-PhCH3)Cr(CO)3 have been examined by means of the linked scan technique. The molecular ion is shown to fragment exclusively by single and multiple CO loss. The ion [C7H8Cr(CO)2]+⋅ also fragments directly to [C7H8Cr]+⋅.
    Additional Material: 2 Tab.
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