ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The Raman and infrared spectra of the superionic protonic conductor CsHSO4(CsDSO4) were investigated in the 18-450 K range. Polarized single crystal Raman and infrared reflection spectra were also studied at room temperature. An assignment of bands due to internal and external vibrations is given in terms of symmetry species and approximate type of motion. The spectroscopic results, in particular the behaviour of the Raman bands as a function of temperature, are used to discuss the crystalline structures of various phases, hydrogen bonding, the type and degree of structural disorder, phase transitions and conductivity.
Additional Material:
9 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250180308
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