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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 3 (1969), S. 403-408 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: A method of testing the tensile strength of the porcelain-gold bond has been developed. Tensile strengths of the bond are improved primarily by the formation of an oxide layer on the gold before baking the porcelain and not by the degree of gross surface roughness. The oxide layer may act either as a transition ayer or it may create microsurface roughness. The gross surface roughness probably complicates the wetting action of the porcelain on the gold. Whether the actual bond is of a chemical nature, physical nature, or both, remains uncertain.
    Additional Material: 3 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 28 (1994), S. 189-194 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The coefficient of thermal expansion of core and veneer porcelains for all ceramic crowns must be compatible to prevent formation of stresses during the firing cycles. The purpose of this study was to use a thermal shock test to evaluate the crazing resistance of six all-ceramic crown systems. The systems tested were: Vita In-Ceream®, Vita Hi-Ceram®, Dicor™ veneered with Vitadur® N, magnesia core veneered with Ceramco® II, magnesia core veneered with Silhouette™, and magnesia core veneered with Vita VMK® 68. A maxillary central incisor was prepared with 1.0 mm axial and 1.5 mm incisal reduction. Refractory dies were prepared and crowns were fabricated using the manufactures recommendations. Six specimens of each system were placed inside a beaker in a furnace at 90°C. After 15 min heat soak, ice water was poured into the beaker through a funnel. The samples were dried in air, reheated, and inspected for crazing using light microscopy. If crazing was observed, this would constitute a failure at a temperature difference (ΔT) of 90°C. If no failure occurred, the test was repeated at increasing temperature increments of 10°C until failure. The crazing resistance of each system, expressed as the mean ΔT, was: 〉 200 (Hi-Ceram®), 152 ± 19 (Dicor™ / Vitadur® N), 143 ± 5 (magnesia core/Vita VMK® 68), 122 ± 21 (magnesia core/Silhouette™), and 118 ± 10 (magnesia core/Ceramco® II) °C. All systems tested resisted crazing due to quenching in ice cold water from 100°C. Systems with lower coefficients of expansion showed significantly greater resistance to thermal shock using ANOVA. © 1994 John Wiley & Sons, Inc.
    Additional Material: 3 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 28 (1994), S. 603-609 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Leucite is a major crystalline component of dental porcelains. The presence of tetragonal leucite in dental porcelains increases their coefficients of thermal expansion due to its high coefficient of thermal expansion (20-25 × 10-6/°C). This is particularly useful for those porcelains designed for bonding to precious metals and nickel alloys. The purpose of this study was to determine the leucite content of selected commercial dental porcelains in relation to their coefficient of thermal expansion values. The weight fraction of leucite was determined with quantitative x-ray diffraction using copper as an internal standard. Coefficient of thermal expansion values were determined using a thermal dilatometric analyzer. Five commercial body porcelains were studied. Leucite was not detected in samples of Vitadur N and Duceram LFC. An ANOVA showed that there was a significant difference in the weight fraction of leucite for Silhouette, Ceramco II, and Optec HSP porcelains. Linear regression revealed a correlation (R = 0.91) between weight fraction of leucite and the coefficient of thermal expansion for those samples containing leucite. Ducram LFC, which is recommended by the manufacturer for use with metals and leucite-containing porcelains, had no detectable leucite although the coefficient of thermal expansion was found to be 13.2 ± 0.4 × 10-6/°C at 25-472°C. A low glass transition temperature contributed to the high average coefficient of thermal expansion value. © 1994 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
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  • 4
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The aging reaction of a 90 wt-% gold, 10 wt-% platinum alloy with nominal iron concentrations of 0.04, 0.08, and 0.16 wt-% iron has been studied using electrical resistance measurements. The electrical resistance was measured as a function of temperature from 300 to 750°C. A decrease in electrical resistance was observed occurring at 350 to 450°C, when heating the solution treated and water quenched specimens containing iron. Subsequent heating and cooling curves follow the gold-platinum standard. Isothermal electrical resistance measurements were made as a function of time. The data from the specimen containing a nominal iron concentration of 0.16 wt-% iron was analyzed using the Johnson-Mehl equation. The shape parameter n was found to vary as a function of aging temperature from n = 0.6 to n = 1. These results have been rationalized in terms of a model involving precipitation of FePt3 at dislocations (400°C) and FePt3 in the shape of a rod at 500°C.
    Additional Material: 6 Ill.
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