ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Analysis of PPMMA films from oxygen plasma using X-ray photoelectron spectroscopy (1994)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 2275-2281 
    Details
    ISSN: 0887-624X
    Keywords: plasma polymerization ; electron beam resist ; X-ray photoelectron spectroscopy ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Plasma polymerized methyl methacrylate (PPMMA) films have been synthesised on silicon substrates in RF glow discharge using oxygen plasma. The electron beam delineation sensitivity of the PPMMA films has been studied systematically by varying oxygen and monomer flow rates. X-ray photoelectron spectroscopy (XPS) analysis clearly illustrates how C/O ratio in the films determines the properties of PPMMA films as electron beam resist. © 1994 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1994.080321209
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Tests of a “free-volume” model of gas permeation through polymer membranes. II. Pure Ar, SF6, CF4, and C2H2F2 in polyethylene (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 24 (1986), S. 2149-2166 
    Details
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Permeability coefficients for Ar, SF6, CF4, and C2H2F2 (1,1-difluoroethylene) in polyethylene membranes were determined from steady-state permeation rates at temperatures from 5 to 50°C, and at applied gas pressures of up to 15 atm. The temperature and pressure dependence of the permeability coefficients was represented satisfactorily by an extension of Fujita's free volume model of diffusion of small molecules in polymers. The parameters required by this model were determined from independent absorption (diffusivity) measurements with the above gases in polyethylene rods. The present work confirms the results of previous studies with CO2, CH4 C2H4 and C3H8 in polyethylene.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1986.090241001
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Isotactic polypropylene foams crystallized from compressed propane solutions (1998)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 617-627 
    Details
    ISSN: 0887-6266
    Keywords: isotactic polypropylene foams ; supercritical propane solutions ; high surface areas ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Crystallization of isotactic polypropylene (iPP) from homogeneous solution in supercritical propane yields open-cell foams of high surface area (120-150 m2/g). Their morphology usually consists of microspheres with a dense core and a porous periphery of radiating fibrils. Pore radii covering the mesopore range (2-50 nm), making their largest contribution at 10-20 nm, were calculated from nitrogen adsorption isotherms. Surface areas of the correct order of magnitude are obtained by assuming that gas adsorption takes place on the surfaces of lamellar crystals. Crystallization of iPP from n-butane and n-heptane generates foams of lower mesoporosity and smaller surface area. These more “liquid-like” solvents do not allow the formation of an open network of mesopores or they promote its collapse upon their removal. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 617-627, 1998
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
  • 4
    Electronic Resource
    Electronic Resource
    Transport of gases in aromatic polyesters: Correlation with WAXD studies (1991)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 29 (1991), S. 921-931 
    Details
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Polymer packing density can be conveniently measured by either density-based measurements (direct or estimated free volume) or wide-angle X-ray diffraction (WAXD) spectra. Previously reported diffusivity and permeability values for various polyarylates and polyimides are examined on the basis of the packing density measured by these different techniques. It is shown that in these rigid glassy polymers, the mean intersegmental distance, the d-spacing, obtained from WAXD provides a better measure of the effect of polymer packing on diffusivity than either direct density measurements or estimated free volumes. It has been possible to correlate previously reported diffusivity and sorption data for various polyarylates and polycarbonate on the basis of the WAXD investigation, using the d-spacing and the amorphous peak width, respectively. The effect of polyarylate structure on d-spacing has been studied. A series of polyarylates have been synthesized with different substituents on the bridge carbon. In this series the d-spacing remains constant while the carbonyl group density and the glass transition temperatures are varied. However, small substituents on the aromatic ring cause significant changes in the d-spacing. These results can be used to tailor polyarylates with desired intersegmental distances and chain flexibility.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1991.090290803
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 5
    Electronic Resource
    Electronic Resource
    Nano-structured, semicrystalline polymer foams (1996)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 34 (1996), S. 3063-3072 
    Details
    ISSN: 0887-6266
    Keywords: nano-structured foams ; semicrystalline polymers ; small-angle scattering ; platelet model ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Semicrystalline polymers gelled from thermally quenched semidilute solutions can, in some cases, be supercritically dried to produce nano-structured foams of exceedingly high specific surface area. This article investigates the nano-morphology of these semicrystalline foams. The common morphological feature that these systems display in small-angle scattering can be described by uncorrelated lamellar platelets. The morphological details, which can be obtained using microscopy and small-angle scattering, indicate that these low-density systems occupy a morphological niche between polymeric crystallites from dilute solutions, and spherulitic crystals derived from concentrated solutions and melts. Because these crystalline morphologies occur in concentration ranges between dilute and concentrated, they may offer simple insight into the mechanisms available for distortion of ideal, dilute-solution-derived crystallites as polymer concentration is increased. Several mechanisms for the observed distortions are proposed. © 1996 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
  • 6
    Electronic Resource
    Electronic Resource
    Polymerization of acrylonitrile using magnetron deposition technique (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 53 (1994), S. 1397-1401 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polymerization of acrylonitrile (PAN) in a capacitively coupled glow discharge under magnetic enhancement was studied. The design aspects of a magnetron electrode and its characteristics are described. The study suggests that an improved magnetron design helps in achieving a higher monomer conversion ratio that improves the quality of films and allows the use of lower system pressure. Thin, uniform, pinhole free films of PAN having very high molecular weight were formed. © 1994 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1994.070531101
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 7
    Electronic Resource
    Electronic Resource
    Dynamic mechanical analysis and interpretation of molecular motions in polyarylatesNCL communication No 5566. (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 54 (1994), S. 1093-1101 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Molecular motions in polyarylates synthesized from substituted bisphenols have been investigated by dynamic mechanical analysis. Substitution at the ring carbon atom results in a more pronounced enhancement in glass transition temperature (Tg) as compared to substitution at the bridge carbon atom. The enhancement in mono and disubstituted polyarylates is more consistent than that in the case of polycarbonates and polysulfones. The β transition has been shown to result from defects in the polymer samples. The molecular motion responsible for the τ transition in polyarylates has been shown to be more iocalized than in the case of polycarbonates. Introduction of the phthalide ring in the isopropylidene unit of bisphenol-A molecule results in splitting of the τ transition peak into two. The results have been compared with those reported for other bisphenol-based polymers, viz. polycarbonates and polysulfones, and explained on the basis of the structural attributes of the polymers. © 1994 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1994.070540812
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 8
    Electronic Resource
    Electronic Resource
    Effect of heat treatment on nylon-6 tire cords (1985)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 30 (1985), S. 4417-4429 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The behavior of nylon-6 tire cords at elevated temperature has been evaluated. The heat treatment of cords at 200°C for 16 h was found to reduce their tensile properties considerably. This has been attributed to the decrease in average molecular weight and change in molecular weight distribution as ascertained by fractionation studies. Heat setting of cords in the temperature range of 180-210°C without any applied tension showed some decrease in tensile properties. This has been ascribed to the higher degree of shrinkage of the cords and hence increased chain folding in the molecular structure. However, irrespective of time and temperature of heat treatment, shrinkage was reduced with increasing tension on the cord. Effect of heat setting on density and crystallinity was also evaluated.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1985.070301117
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 9
    Electronic Resource
    Electronic Resource
    Evaluation of adhesion characteristics of nylon-6 tire cord to natural rubber (1987)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 34 (1987), S. 913-918 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The adhesion characteristics of Nylon-6 cords to rubber matrix, using Resorcinol Formaldehyde Latex (RFL) solution, were evaluated at various conditions. The heat-setting studies of RFL dipped cords in the temperature range of 180-210°C showed a loss in tensile properties. However, a minimum in the loss was observed when a pretension load was given to the cords. Percent shrinkage of RFL-dipped cords increased with the increase in temperature of heat setting. Adhesion behavior of Nylon-6 cords to rubber matrix showed some improvement under relaxed conditions in the entire temperature range studied. With the application of suitable tension to cord, adhesion behavior can be made constant. This has been attributed to the higher extent of shrinkage of cords under relaxed conditions providing greater cord surface area. This in turn, leads to increased cord to rubber matrix.
    Additional Material: 7 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1987.070340304
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 10
    Electronic Resource
    Electronic Resource
    Mass spectrometric studies of sulfonyl esters of diazonaphthalenones: Relationship between fragmentation patterns and photolithographic mechanisms (1987)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 34 (1987), S. 447-467 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Esters of 2-diazonaphthalenone sulfonic acid were examined by mass spectrometry using electron impact and chemical ionization techniques. Charactristic differences in the fragmentation patterns of positional isomers have been observed. In a manner analogous to photo-induced decompositions, the diazoketo functional groups fragment by elimination of N2 to form an indenoketene ion. An alternative process involves the apparent loss of 26 mass units from the molecular ion. The latter process is explained by evoking the abstraction of two hydrogen atoms following the loss of N2. With deuterium isotope labeling, it has been shown that the hydrogens are abstracted from the surface of the probe tip used for introduction of the samples into the mass spectrometer. It is concluded that an environment rich in hydrogen or proton-donating properties promotes and enhances the incorporation of the hydrogen atoms and formation of the [M-26] species at the expense of the ketene moiety, which is an important intermediate in the photoresist process. By extrapolation it may be inferred that the efficiency of the photolithographic process could be influenced by the availability of protons in the photoresist matrix.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1987.070340201
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...