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Kinetics of 4-tert-butylphenol hydrogenation over rhodium (1997)

Konuspaev, Sapar R. ; Zhanbekov, Khairulla N. ; Kul'Kova, Natalya V. ; [et al.]

Weinheim : Wiley-Blackwell

Chemical Engineering & Technology - CET 20 (1997), S. 144-148

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ISSN: 0930-7516

Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology

Notes: The kinetics of the liquid phase hydrogenation of 4-tert-butylphenol to form cis- and trans- 4-tert-butylcyclohexanol at 1.0-10.0 MPa and 40°C in isopropanol over a Rh catalyst has been studied. The kinetic behavior of this parallel system is described by a proposed reaction network. Keto-enol tautomeric transformation of adsorbed 4-tert-butyltetrahydrophenol and 4-tert-butylcyclohexanone is thought to be a key step, which governs the stereoselectivity of the overall complex reaction of alkylphenol hydrogenation.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/ceat.270200212

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