ISSN:
0449-2978
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The glass transitions of an ionic polymer in bulk have been studied as a function of the counterion for various homo- and copolymers. It is shown that the glass transition temperature can vary by as much as 530°C., from -10°C. for the nonionic material to +520 for Ca2+ or Zn2+ substituted polymer. From simple electrostatic considerations, it is shown that a linear correlation should exist beween the glass transition and the ratio of the cation charge, q, to the internuclear distance, a, between cation and chain anion; for this particular material (the polyphosphate chain) the relation is Tg = 625(q/a) -12 where q is in units of one electron and a is in A. If the data are interpreted in the light of the Gibbs-DiMarzio theory, it is seen that both the chain stiffness and the intermolecular energy increase in an approximately parallel manner as q/a increases.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1966.160040603
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