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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 2203-2214 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The one-component steady-state permeation of gases through a silicalite-1 zeolite composite membrane as a function of the temperature is studied from 190 to 680 K for light hydrocarbons, noble gases, and some inorganic gases. In general, with increasing temperature the permeance shows a maximum followed by a minimum. For gases weakly adsorbed the permeance has only a minimum and for gases strongly adsorbed only a maximum is observed in the permeance. The permeance for various gases, for a feed pressure of 101 kPa, span four orders of magnitude. The lowest permeation is for i-butane at 300 K: a permeance of 0.07 × 10-8 mol. m-2.s-1.Pa-1. The highest value is observed for methane: a permeance of 70 × 10-8 mol. m-2.s-1.Pa-1 at about 240 K. A comparison between the isobars and the temperature dependence of the steady-state permeance, both at 101 kPa, shows that at the temperature where the amount adsorbed vanishes the permeance starts to increase. The temperature dependence of the steady-state fluxes through the silicalite-1 membrane can be described only if two diffusion mechanisms are taken into account. For high occupancies the mass transport can be described by equilibrium adsorption followed by surface diffusion and for low occupancies the mass transport can be described by activated gaseous diffusion. With increasing temperature the mass-transport mechanism shifts from the surface diffusion regime to the activated gaseous diffusion regime. With these two diffusivities modeling results agree well with experimental results for the one-component flux through the silicalite-1 zeolite membrane.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 385-396 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The oxidation of CO by O2 and N2O over an oxidized 10 wt. % Cu-Cr/Al2O3 catalyst (Cu:Cr=1:1) has been studied by temperature-programmed reactivity measurements (400-550 K) over a wide range of partial reactant pressures, including inhibition by CO2. The CO oxidation rate is zeroth-order in oxygen and has orders between 0-1 in CO and N2O, depending on the gas-phase composition. Mechanistic information from literature combined with the kinetic data resulted in the selection of an Eley-Rideal-type of kinetic model without a priori assumptions on rate-determining processes. The model consists of the oxidation of reduced sites by O2 and/or N2O, followed by a reaction with CO, yielding a surface intermediate that releases CO2 in a consecutive step. CO2 inhibits both by reversible adsorption on oxidized and reduces sites, the latter under formation of the surface reaction intermediate. Apart from the surface oxidation by O2, the reaction rates of all assumed elementary processes are of the same order of magnitude and, therefore, determine the overall rate. The surface oxidation by oxygen is about four orders of magnitude larger, which explains the zeroth-order in oxygen and the observation that oxygen first reacts with CO before N2O is able to oxidize CO. The obtained activation energies of the elementary processes agree with values in the literature for corresponding systems.
    Additional Material: 7 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 837-846 
    ISSN: 1434-193X
    Keywords: Friedel-Crafts reaction ; Hydroxyalkylation ; Aromatics ; Epoxides ; Zeolites ; Clays ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Solid acids, such as zeolites and clays, catalyse the intramolecular hydroxyalkylation (cyclialkylation) of several arylalkyl epoxides in moderate to excellent conversions and selectivities. The use of solid acids in these cyclialkylations provides a cleaner, better alternative to conventional Lewis and Brønsted acids, enabling a more facile workup of reaction mixtures and, in several cases, better selectivities.
    Additional Material: 3 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 11 (1994), S. 442-452 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effects of a concentric annular air jet on the structure of a liquid spray have been examined under isothermal conditions using Phase Doppler interferometry, and flow visualization techniques. Local measurements of drop size, velocity, volume flux, and number density have been made simultaneously and non-intrusively. The results show that the initial spray cone widens substantially with increasing air flow while the overall spray envelope remains essentially the same. The air jet creates a narrow high mass flux region of small droplets in the core of the spray, surrounded by a nearly uniform flux region extending almost to the boundary of the spray. Line averaged mean diameters are found to be slightly smaller, indicating that the annular air jet plays a role improving the atomization process as well.
    Additional Material: 19 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 12 (1995), S. 225-231 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method has been developed to increase the sensitivity of phase Doppler interferometry-based particle sizing systems to small particles in the presence of a spray containing large and small droplets; an important consideration when using seed particles to track the gas-phase velocity in multi-phase flows. The method, applicable to PDPA systems configured to operate in first and higher order refraction mode, involves doping the sprayed liquid with a dye that is strongly absorbing at the incident laser wavelengths. This results in greatly diminished scattered intensity from larger droplets, thus allowing the photomultiplier gain to be set to a level sufficient to easily detect small particles without saturation. Tests conducted indicate that, at a collection angle of 30° and droplet absorptivity of γ = 0.014/μm, the PDPA can accurately size absorbing droplets up to approximately 200 μm. This upper limit can be extended by changing selection angle. Tests performed with an actual spray demonstrated that the method allowed detection of 1 μm to 235 μm droplets; more than four times the instrument's usual range of 50: 1. A data correction scheme to determine the effective probe volume radius for each particle size class has been developed for absorbing particles, as standard correction schemes derived for non-absorbing droplets excessively weigh distributions toward smaller particles.
    Additional Material: 10 Ill.
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  • 6
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 54 (1941), S. 14-21 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 42 (1929), S. 257-262 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 10 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 45 (1932), S. 180-181 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 48 (1935), S. 585-586 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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