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  • Analytical Chemistry and Spectroscopy  (3)
  • Industrial Chemistry and Chemical Engineering  (1)
  • Wiley-Blackwell  (4)
  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 10 (1975), S. 867-873 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Composite metastable peaks are generated in the unimolecular fragmentations (i) [C3H5]+ → [C3H3]+ + H2 (flat-top upon flat-top) and (ii) [C4H9]+ → [C3H5]+ + CH4 (flat-top and gaussian). The measurement of appearance potentials and kinetic energy releases lead us to conclude, in agreement with earlier proposals, that in (i) the components can arise from the generation of the isomeric cyclopropenium and propargyl daughter cations. In (ii) the components are proposed to arise from the fragmentation of tert- and sec-butyl cations yielding allyl as the common daughter ion.The composite peak observed in the fragmentation (iii) [C3H4]+· → [C3H3]+ + H· is shown to be present only if the decomposing molecular ion is large enough to also produce [C6H8]2+ ions. The second component in (iii) then arises from the reaction [C6H8]2+ → [C6H6]2+ + H2.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 16 (1981), S. 236-236 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 13 (1978), S. 133-134 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The dish-topped metastable peak for the fragmentation [C3H7]+ → [allyl]+ + H2 is generated by the threshold fragmentation. The fraction of the reverse activation energy which is partitioned as translational energy of the products is 0.9 ± 0.1. It is proposed that a similar partitioning coefficient applies to the excess internal energy above threshold.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 5 (1991), S. 131-134 
    ISSN: 0268-2605
    Keywords: Ceratocystis ulmi ; fungi ; aggressive and non-aggressive strains ; wild strains ; Dutch elm disease ; organotins ; triphenyltins ; tricyclohexyltin ; fungicide ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The effect of triorganotin compounds, R3SnX, on the growth of three wild strains of Ceratocystis ulmi (C. ulmi) fungus, two aggressive and one non-aggressive strains, was evaluated in shake culture. In all cases, the triphenyltins were the more effective organotins for the inhibition of C. ulmi in vitro. The anionic group, X, did not have a significant role in the inhibition, suggesting that the species involved in the inhibition is the triphenyltin moiety (Ph3Sn+) or the hydrated triphenyltin moiety (Ph3Sn(H2O)+2). It is further suggested that the triphenyltin species Ph3SnOH and Ph3SnOAc are the preferred compounds for the control of Dutch elm disease. The tolerance of aggressive isolates to fungitoxins appears to depend more on the nature of the fungicide than on the type of fungus.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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