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  • 1
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The aquiferous systems of three common, coastal, marine Demospongiae, Halichondria panicea (Pallas), Haliclona permollis (Bowerbank) and Microciona Prolifera (Ellis and Solander), are analyzed by measurements of cross-sectional areas of conducting elements. The patterns in demosponges of extremely different organizational morphologies are found to be quantitatively similar. The porocyte nature of the ostia is established for all three species. Choanocyte chamber densities range from 1 to 1.8 × 107 chambers ml-1 with 57 to 95 choanocytes per chamber (means). Cross-sectional area of the intervillar space of the choanocyte collars is calculated to be 12 to 56 times the lateral surface area of the specimen. Velocities of water movement through specific elements of the aquiferous system are calculated from cross-sectional area data and measured oscular flow of Haliclona permollis. The calculated Reynolds numbers lie below the critical value and fluid flow is thus considered laminar throughout the aquiferous systems of these sponges.
    Additional Material: 3 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 5 (1967), S. 431-454 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The relationships between molecular weight distribution and structure in polymerizations with long-chain branching were reviewed and extended. Results were applied to an experimental examination of intrinsic viscosity in polydisperse, trifunctionally branched systems. Several samples of poly(vinyl acetate) were prepared by bulk polymerization under conditions of very low radical concentration. The relative rate constants for monomer transfer, polymer transfer, and terminal double-bond polymerization were established from the variation of Mn and Mw with the extent of conversion. Average branching densities were then calculated for each sample and ranged as high as 1.5 branch points/molecule. Intrinsic viscosities [η]B were measured in three systems: a theta-solvent, a good solvent, and one that was intermediate in solvent interaction. These results were compared with calculated viscosities, [η]L, which would have been observed if all the molecules had been linear. The values of [η]B/[η]L were substantially the same in all three solvents. The variation of this ratio with branching density was compared with the theory of Zimm and Kilb as adapted to polydisperse systems. Discrepancies were noted, and the adequacy of present model distribution functions for branched polymers was questioned.
    Additional Material: 6 Ill.
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  • 3
    ISSN: 0887-6134
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The fast atom bombardment (glycerol) and 252Cf plasma desorption mass spectra of 16 simple monoglucosyl conjugates have been compared. Plasma desorption mass spectrometry, in general, has been found to be the superior technique for characterizing these low molecular weight conjugates because of the relative absence of interfering matrix peaks.
    Additional Material: 2 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 15 (1973), S. 951-962 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Carrier-bound immobilized α-amylases and glucoamylase have been obtained by photopolymerizing aqueous solutions containing acrylamide, a crosslinking monomer, an enzyme-reactive monomer, an oxygen scavenger, and amylase, and allowing the amylase to react with the entrapping enzyme-reactive gel matrix evolved. Partial starch hydrolyzates (28 DE corn starch syrup) have been continuously converted to 90-94% dextrose syrups in columns packed with immobilized amylases. The enzymatic heat stability of immobilized glucoamylase gels is discussed.
    Additional Material: 2 Tab.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 79 (1967), S. 616-617 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 6
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The storage and loss shear moduli, G′ and G″, have been measured for dilute solutions of bovine fibrinogen in 68% aqueous glycerol and of intermediate fibrin polymer in 6M hexamethylene glycol, by the Birnboim-Schrag multiple-lumped resonator apparatus with titanium alloy resonators. The frequency range was 100-5800 Hz, the concentration range 1-6 g/l., and the temperatures 10.0 and 25.0°C. The shear moduli G′ and G″ at finite concentration, and the extrapolated instrinsic shear moduli [G′] and [G″], as functions of frequency, were compared with the predictions of various molecular theories. For fibrinogen, the frequency dependence agreed quite well with the calculations of Hassager for a trinodular rod as modified for the presence of small amounts of dimeric and trimeric aggregates which were deduced from parallel measurements of oscillatory flow birefringence. It was not possible, however, to distinguish between a linearly rigid configuration and one which is freely jointed at the central nodule. A model of a soft elastic sphere (simulating the cage model of Köppel) appeared to be very unlikely. The relaxation time for a rigid trinodular rod and the longest relaxation time for a jointed trinodular rod, calculated from molecular dimensions on the basis of electron microscope measurements, are somewhat smaller than the corresponding observed values; the discrepancy suggests that the molecule is swollen in solution. For the intermediate polymer (which was formed under conditions where ligation is expected), the frequency dependence agreed quite well with that predicted either for a prolate ellipsoid (Cerf-Scheraga-Saitō) or for a cylindrical rod (Yamakawa). The relaxation time obtained by fitting to theory agrees quite well with that calculated for a cylindrical rod with molecular dimensions based on a degree of polymerization of 20 and lateral binary association with staggered overlapping.
    Additional Material: 5 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 22 (1983), S. 1747-1758 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The frequency dependences of the storage and loss shear moduli, G′ and G″, of pronase-treated collagen dissolved in acetate buffer at pH 4.0 were measured at 17.0°C by use of the Birnboim-Schrag multiple lumped resonator apparatus. Some of the solutions contained 70% glycerol. The infinite-dilution moduli were determined and compared with theoretical models for a rigid cylinder and a semiflexible rod. Only the latter could fit the data. A rotational time of 144 μs and a slowest flexural relaxation time of 21 μs, both reduced to water at 20°C, were determined from the fit. The intrinsic viscosity and rotational relaxation time correspond to a semiflexible rod with persistence length of about 170 nm and a Young's modulus of 4 × 1010 dyn/cm2.
    Additional Material: 3 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 338-351 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A machine has been designed and constructed which is capable of evaluating high strength parachute components in the laboratory at impact speeds ranging from 200-750 ft./sec. The system consists mainly of a device for propelling various masses with photographic instrumentation for observing the impact. Measurement of missile deceleration gives applied force. Extension is measured for changes in gage marh on the test specimen. Energy absorbed can be calculated from the displacement of two ballistic pendulums. Results reveal that a t impact speeds force and strain waves are generated within the material which cause rapid changes in the forces measured. A theory has been proposed to explain this behavior. Energy measurements indicate a potential change in the stress-strain curve of nylon webbings and joints during impact. Improvements in energy absorption result.
    Additional Material: 15 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 269-277 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The stress-strain properties of isotactic polypropylene yarn have been studied over a wide range of strain rates up to 2,000,000% per minute. The testing equipment used included the Instron, three pneumatic and pneumatichydraulic type of high speed testers, the falling weight method, the rotating disc longitudinal impact and ballistic techniques. Evaluation of the behavior of polypropylene at strains of 2, 6, 12, and 16% shows the existence of two relaxation peaks, one at τ = 10-2 sec. and the other at about 102 sec. with a plateau of little time dependency in between. The data, especially at the shorter testing times, can be well represented by a single mechanical model composed of two Maxwell units in parallel. Information concerning the ultimate properties of isotactic polypropylene yarn was also obtained. The work-to-rupture values for polypropylene at most strain rates exceed those characteristic of any other available textile material.
    Additional Material: 11 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 1 (1974), S. 207-208 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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