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Viscosity of nonelectrolyte liquid mixtures. III Binary mixtures of methyl methacrylate with hydrocarbons, haloalkanes, and alkylamines (1994)

Oswal, S. L. ; Patel, B. M. ; Shah, H. R. ; [et al.]

Springer

International journal of thermophysics 15 (1994), S. 627-645

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ISSN: 1572-9567

Keywords: Alkylamine ; aromatic hydrocarbons ; binary liquid mixtures ; cyclohexane ; density ; Gibbs energy of activation ; haloalkanes ; η-hexane ; molecular interactions ; viscosity

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract Measurements of the viscosityη and the densityϱ are reported for 14 binary mixtures of methyl methacrylate (MMA) with hydrocarbons, haloalkanes, and alkylamines at 303.15 K. The viscosity data have been correlated with equations of Grunberg and Nissan, of McAllister, and of Auslaender. Furthermore, excess viscosityΔ Inη and excess Gibbs energy of activationΔG* E of viscous flow have been calculated and have been used to predict molecular interactions occurring in present binary mixtures. The results show the existence of specific interactions in MMA + aromatic hydrocarbons, MMA + haloalkanes, and MMA + primary amines.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01563791

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