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  • 1
    Publication Date: 2020-05-18
    Description: The effects of temperature and moisture on flexural and thermomechanical properties of neat and filled epoxy with both multiwall carbon nanotubes (CNT), carbon nanofibers (CNF), and their hybrid components were investigated. Two regimes of environmental aging were applied: Water absorption at 70 °C until equilibrium moisture content and thermal heating at 70 °C for the same time period. Three-point bending and dynamic mechanical tests were carried out for all samples before and after conditioning. The property prediction model (PPM) was successfully applied for the prediction of the modulus of elasticity in bending of manufactured specimens subjected to both water absorption and thermal aging. It was experimentally confirmed that, due to addition of carbon nanofillers to the epoxy resin, the sorption, flexural, and thermomechanical characteristics were slightly improved compared to the neat system. Considering experimental and theoretical results, most of the epoxy composites filled with hybrid carbon nanofiller revealed the lowest effect of temperature and moisture on material properties, along with the lowest sorption characteristics.
    Electronic ISSN: 2073-4360
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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  • 2
    Publication Date: 2019-12-20
    Description: Epoxy resin composites with different weight fractions of TiO2 microparticles (1%, 5%, 10%, 15%, 20%) and of TiO2 nanoparticles (0.5%, 1%, 2%, 3%) were prepared. The particle size of the nanoparticles was averaged around 21 nm while the particle size of the micro TiO2 particles was averaged around 0.2 μm. The morphology of the manufactured particulate composites was studied by means of scanning electron microscopy (SEM). The mechanical properties of both nanocomposites (21 nm) and microcomposites (0.2 μm) were investigated and compared through flexural testing. Furthermore, the effect of displacement-rate on the viscoelastic behavior of composite materials was investigated. The flexural tests were carried out at different filler weight fractions and different displacement-rates (0.5, 5, 10, 50 mm/min). The influence of TiO2 micro- and nanoparticles on the mechanical response of the manufactured composites was studied. For micro TiO2 composites, a maximum increase in flexural modulus on the order of 23% was achieved, while, in the nanocomposites, plastification of the epoxy matrix due to the presence of TiO2 nanoparticles was observed. Both behaviors were predicted by the Property Prediction Model (PPM), and a fair agreement between experimental results and theoretical predictions was observed.
    Electronic ISSN: 2073-4360
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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  • 3
    Publication Date: 2021-03-23
    Description: The response of fiber-reinforced polymer composites to an externally applied mechanical excitation is closely related to the microscopic stress transfer mechanisms taking place in the fiber–matrix interphasial region. In particular, in the case of viscoelastic responses, these mechanisms are time dependent. Defining the interphase thickness as the maximum radial distance from the fiber surface where a specific matrix property is affected by the fiber presence, it is important to study its variation with time. In the present investigation, the stress relaxation behavior of a glass fiber-reinforced polymer (GFRP) under flexural conditions was studied. Next, applying the hybrid viscoelastic interphase model (HVIM), developed by the first author, the interphase modulus and interphase thickness were both evaluated, and their variation with time during the stress relaxation test was plotted. It was found that the interphase modulus decreases with the radial distance, being always higher than the bulk matrix modulus. In addition, the interphase thickness increases with time, showing that during stress relaxation, fiber–matrix debonding takes place. Finally, the effect of fiber interaction on the interphase modulus was found. It is observed that fiber interaction depends on both the fiber–matrix degree of adhesion as well as the fiber volume fraction and the time-dependent interphase modulus.
    Electronic ISSN: 2073-4360
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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