ISSN:
0887-624X
Keywords:
poly(ester-amide)s
;
bis(2-oxazoline)s polymerization
;
bulk polymerization
;
glass transition temperature
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The preparation of linear poly(ester-amide)s from monoanhydrides, bis(2-oxazoline)s (namely 2,2′-(1,4-phenylene)bis(2-oxazoline)) and a third comonomer is discussed. The polymerization reactions were carried out in bulk between 150 and 200°C. When the third monomer is a diol, poly(ester-ester-amide)s are obtained. Diols of different structure were used: α,ω-diols having up to 12 carbon atoms, ethylene glycol oligomers (two or three repeating units), cyclic diols, etc.; glutaric, 3,3-dimethylglutaric and maleic anhydrides were used as monoanhydrides. The polymers were studied from the point of view of thermal properties, finding a substantial agreement between the structure of the monomers and the glass transition temperature of the polymers. By using primary diamines as a third comonomer, the reaction does not lead to the formation of a polymeric product. The failure of the polymerization was attributed to a competitive reaction that prevents the polymerization. After the amine group has reacted with the anhydride, cyclization of the so-formed carboxyalkylamide occurs, giving an imide derivative, unable to react further. Therefore, only a mixture of low molecular weight compounds is obtained in this case. When the diamine is secondary, the imidization reaction is not possible, and linear poly(amide-ester-amide)s are obtained. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 3241-3248, 1997
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
Permalink
