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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 338 (1996), S. 558-563 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Development of an Automated Trace-Matrix Separation Technique for the Determination of Trace Metals in Pure Titanium and TitaniumdioxideThe determination of metal traces in pure titanium with ICP-AES or ICP-MS requires an effective trace-matrix separation technique to eliminate interferences. After digestion in HF and HNO3 the traces can be separated from the matrix using a cation exchanger column. A computer controlled pumping system is used for the automatic control of the procedure of preconcentration, elution and determination. The method requires a minimum of chemical manipulation and reduces the risk of contamination by using only subboiled acids. Recovery rates of more than 90% and high precision are obtained for 16 analytes. For most of the elements detection limits in the range of 1 to 10 ng/g titanium can be achieved.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 1980-09-01
    Description: The vertical clay mineral distribution pattern in two sediment cores taken from two East African lakes has been studied in detail. In the core from Lake Albert (Mobutu Sese Seko) a clay assemblage consisting principally of smectite with some illite and kaolinite in the uppermost segment of the core changed with depth into first a mixed-layer illite-smectite dominated clay and then at 6·60 m into an iltite dominated clay. Lower in the core there was again a transition towards interlayer mixtures, and in the bottom segment towards smectite. These changes are interpreted as a diagenetic transformation of smectite into illite, effected by saline palaeo-lake water with an unusually high K/Na ratio. Three smectite→illite-smectite→illite transition cycles were recognized in a 56 m deep sediment core from Lake Manyara. The sections in which illite dominated contained silt-sized analcime, while those with interlayer mixtures contained alkaline zeolites. The diagenetic illitization of smectite appeared to parallel the process of analcime formation, the K necessary for illitization being released during K,Na-zeolite→analcime transformation. These occurrences suggest that high temperature and pressure may not constitute absolute prerequisites for the diagenetic illitization of smectite.
    Print ISSN: 0009-8558
    Electronic ISSN: 1471-8030
    Topics: Geosciences
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  • 3
    Publication Date: 1987-09-01
    Description: The clay fractions from a 1191-cm long sediment core in the SW Basin of the Atlantis II Deep, Red Sea, were investigated by XRD, electron microscopy and chemical analysis. Talc dominates in the botton portion of the core, near the brine discharge vent. At 1183 cm depth, the clay consists of vermiculite/chlorite and chrysotile. These minerals are of hydrothermal origin and two possible formation pathways are proposed: (i) vermiculite/chlorite and chrysotile formed by the submarine alteration of previously deposited talc; (ii) vermiculite/chlorite and chrysotile authigenically precipitated as a result of changes in the chemical composition of the brine. At 1170 cm depth, a new depositional sequence results from the progressive alteration of swelling 2:1 minerals into vermiculite. At 1025 cm, Mg-rich clay minerals such as chlorite, chrysotile and talc again become prominent. The upper part of the core is characterized by a transition from non-expanding Mg-rich clay minerals to Fe-rich expanding clays, principally nontronite. Periodically, the content of well-crystallized oxides such as hematite in the layers increases. At 1025 cm, some of the Fe-oxides have a morphology similar to that of akaganéite. In the uppermost part of the core, iron oxides appear to consist of a poorly crystalline hydrothermal hematite. An attempt has been made to correlate the various mineralogical assemblages geochemically.
    Print ISSN: 0009-8558
    Electronic ISSN: 1471-8030
    Topics: Geosciences
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