ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title compound, 4-ammonio-2,2,6,6-tetramethylpiperidinium chromate dihydrate, (C9H22N2)[CrO4]·2H2O, crystallizes in the monoclinic system with one organic cation and one chromate anion in the asymmetric unit, together with three independent sites for water molecules, two of which have their O atoms located on twofold axes. The structure is composed of layers built up from CrO42− tetrahedra and water molecules alternating with C9H22N22+ cations and additional water molecules. Two types of hydrogen bonds, O—H...O and N—H...O, ensure the cohesion and stability of the structure.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270101008447
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