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  • 1
    Publication Date: 2020-03-03
    Description: The island of Pantelleria is one of the best known localities of bimodal mafic-felsic magmatism (alkali basalt and trachyte-pantellerite). Among the felsic rocks, the coexistence in a single eruption of products of both trachyte and pantellerite compositions is limited to few occurrences, the Green Tuff (GT) ignimbrite being one of these. The GT is compositionally zoned from pantellerite (70.1 wt% SiO2, mol Na+K/Al = 1.86, 1871 ppm Zr) at the base to crystal-rich (〉30 vol%) comenditic trachyte (63.4 wt% SiO2, mol Na+K/Al = 1.10, 265 ppm Zr) at the top, although the pantellertic compositions dominate the erupted volume. We present here new data on melt inclusions (MIs) from the pantellerite portions of the GT eruption and, most importantly, from the trachyte member, which have not been studied in-situ by previous work focused on the GT. We document the first occurrence of trachytic melt inclusions in the late-erupted member, whose importance resides in the fact that trachytes were known mostly as crystal-rich lavas or ignimbrites, all variably affected by crystal accumulation. Besides the obvious inferences on the interplay between parental-derivative magmas, this evidence adds also some helpful elements in understanding zoning of silicic and peralkaline (i.e. low-viscosity) magma chambers. Trace elements compositions of MIs reveal that trachyte melts are of two types: (i) a low-Ba, directly descending from basaltic melts by 60-70 % of fractional crystallisation, and (ii) a high-Ba that might be affected by processes of feldspar dissolution and entrainment of the resulting small-scale melts in some MIs. MIs hosted in the deep-seated trachyte body are H2O-poor (≤ 1.2 wt %) with respect to the early erupted (and shallower) pantellerite magma (≤ 4.2 wt %), raising the possibility that either trachyte magma was H2O-undesaturated, or clinopyroxene hosted melt inclusions which suffered consistent H2O loss.
    Description: Published
    Description: VO09
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Melt inclusions; Zoned ignimbrite; Trachyte; Peralkaline rhyolite; Pantelleria. ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-03-03
    Description: In this study we applied petrochemical methods (SEM-EDS; FT-IR) in order to characterize a group of obsidian flakes collected at Ustica island (Sicily). Despite the absence of obsidian geological outcrops, a lot of obsidian fragments still emerging from the lands of Ustica testify that the island was a major import center of obsidian during the prehistory. On this island, there are some prehistoric settlements, dated from the Neolithic to the Middle Bronze Age (6000- 1200 BC), in which the use of obsidian continued until the beginning of metals age. Our study includes: i) Macroscopic and microscopic optical observations, which allowed selecting 18 obsidian flakes (starting from 50 obsidian flakes) on the base of their morphological characteristics. ii) Density measurements (hydrostatic balance). iii) Scanning electron microscope determination (SEM-EDS) of major elements of the obsidian glasses and minerals. Results of our analyses were compared with 12 geological samples collected in obsidian sources from Monte Arci (Sardinia), Palmarola, Lipari and Pantelleria, i.e. the four most exploited obsidian sources of the ancient world in the Western-Central Mediterranean. This study confirms the presence of the Lipari and Pantelleria sources (Sicily) in our obsidian set. iv) We also determined (by FT-IR) the hydration degree of some obsidian flakes in order to detect a possible hydration gradient between the rim and the core of the flake sample. The width of the hydration rim, if any, can be used for an approximate evaluation of the age of the tool.
    Description: Published
    Description: VO13
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Obsidian, Petrographic study, FT-IR, Mediterranean obsidians, Ustica Island. ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-10-06
    Description: Pantelleritic pumice fall on the northern slopes of M. Grande have built a complex sequence of interfingered deposits emitted by closely spaced eruptive vents which are frequently associated with dome-building phases and pantelleritic lavas flows. Field relationships allowed us to recognize eight eruptive units, all lying above the Montagna Grande trachytes. As a whole, petrochemical characteristics of the erupted products indicate an evolutionary trend in which Na-clinopyroxene was the liquidus phase, followed by alkali feldspar. Amphibole and quartz are late-crystallizing, whereas aenigmatite is both early- and late-crystallizing as well. Aenigmatite and Na-clinopyroxene crystallization buffers efficiently the increase of agpaicity, induced by feldspar crystallization, to values of agpaitic index 〈2.0. Some eruptions are characterized by distinctive mineral assemblages: the couple amphibole + aegirine occurs in the Fastuca tephra, whilst the fayalite + ilmenite + quartz association characterizes the Randazzo tephra. The Fastuca eruption, the most powerful among those studied, tapped a reservoir characterized by lower temperature and highly reducing conditions in comparison with the other eruptions. The frequent coexistence of Na-rich and Na-poor pyroxenes, may result from syn-eruptive mixing among variably evolved pantelleritic magmas. The occurrence of late-precipitated halite witnesses the exsolution of a Cl-rich brine during magma ascent.
    Description: Published
    Description: 191-208
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: Pantellerites ; Pantelleria ; peralkaline magmatism ; halite ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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