ALBERT

Description: Highlights: • The central uplift of the Manicouagan impact structure has been dated by (U–Th)/He • A (U–Th)/He central age (207.1 ± 6.4 Ma, 2 standard error, n = 40) has been determined • This age reflects the rapid uplift, cooling and closure of He in ~ 1 Gyr-old titanites • This correlates with the previously determined U–Pb impact-melt age of 214 ± 1 Ma • Our new approach enables dating complex impact structures that lack impact melt rocks Abstract Forty titanite grain fragments from 9 central uplift samples of metamorphosed anorthosite from the Manicouagan impact structure were dated by the (U–Th)/He technique. A (U–Th)/He central age of 207.1 ± 6.4 Ma (2 standard error (SE), n = 40) has been determined. With 4 outlier ages removed the central age is refined to 208.9 ± 5.1 Ma (2 SE). Both of these ages are within error of the previously determined U–Pb zircon age of 214 ± 1 Ma (2σ) derived from the impact melt. Manicouagan's central uplift formed due to rapid elevation from ~ 7–10 km depth as part of the modification stage of the impact process, which has facilitated the dating of its emplacement due to resulting rapid exhumation and cooling and closure of the (U–Th)/He system in titanite. Correlation with the previous U–Pb zircon 214 ± 1 Ma impact melt crystallization age indicates that the (U–Th)/He titanite dating technique offers a new approach to dating complex impact structures in the absence of viable melt sheets, or other melt products. The youngest ca. 195 Ma (U–Th)/He dates preserved in some titanite fragments are synchronous with Early Jurassic, rift-induced lithospheric thinning and associated igneous activity that defines the Central Atlantic Magmatic Province (CAMP). The (U–Th)/He titanite data from Manicouagan indicate that the influence of this regional event may extend west of the previously proposed limit of CAMP activity.

Description: The (U–Th)/He method has been applied to constrain the formation ages of the Clearwater West and East impact structures of Quebec, Canada. Zircons were separated from impact melt samples derived from a surface exposure at Clearwater West (32 km diameter), and from a drill core at Clearwater East (26 km diameter). The (U–Th)/He results indicate ages of 280±27 Ma (2σ, n=7) for Clearwater West, and 450±56 Ma (2σ, n=8) for Clearwater East. Our (U–Th)/He date for Clearwater West supports the findings of previous Rb–Sr (266±15 Ma; 2σ) and 40Ar/39Ar (280±4 Ma and 283.8±2.2 Ma, 2σ) impact melt studies. Our (U–Th)/He date for Clearwater East also overlaps with previously published 40Ar/39Ar dating results, which yielded U-shaped spectra, with ‘maximum’ and ‘best-estimate’ dates of ∼ 460–470 Ma. Our results support the contention, previously based solely on 40Ar/39Ar data, that the Clearwater West and East impact structures do not comprise an impact doublet that formed coevally from a binary asteroid pair.