ALBERT

Description: The Surface Ocean CO2 Atlas (SOCAT), an activity of the international marine carbon research community, provides access to synthesis and gridded fCO2 (fugacity of carbon dioxide) products for the surface oceans. Version 2 of SOCAT is an update of the previous release (version 1) with more data (increased from 6.3 million to 10.1 million surface water fCO2 values) and extended data coverage (from 1968–2007 to 1968–2011). The quality control criteria, while identical in both versions, have been applied more strictly in version 2 than in version 1. The SOCAT website (http://www.socat.info/) has links to quality control comments, metadata, individual data set files, and synthesis and gridded data products. Interactive online tools allow visitors to explore the richness of the data. Applications of SOCAT include process studies, quantification of the ocean carbon sink and its spatial, seasonal, year-to-year and longerterm variation, as well as initialisation or validation of ocean carbon models and coupled climate-carbon models.

Description: Soot oxidation with NO (in the absence of gas phase O 2 ) on potassium-supported Mg-Al hydrotalcite mixed oxides (K/MgAlO) was studied using a temperature-programmed reaction and in situ FTIR techniques. Nitrite and the ketene group were identified as the reaction intermediates and thus a nitrite-ketene mechanism was proposed in which surface active oxygen on K sites of K/MgAlO is transferred to soot by NO through nitrites. In the absence of gas phase O 2 , soot oxidation with NO at lower temperatures (below 450 °C) is limited by the amount of active oxygen on the K sites. This kind of active oxygen is not reusable but can be replenished in the presence of gas phase O 2 . Soot oxidation with NO on K/MgAIO was studied by temperature-programmed reaction and in situ FTIR. The nitrite and the ketene group were identified as the reaction intermediates and thus a nitrite–ketene mechanism was proposed, in which surface active oxygen on K sites is transferred to soot by NO through nitrites, forming the ketene group.

Description: Niobium and Ta concentrations in ultrahigh-pressure (UHP) eclogites and rutile from these eclogites and associated high pressure (HP) veins were used to study the behaviour of Nb–Ta during dehydration and fluid-rock interaction. Samples were collected through a ∼2 km profile at the Bixiling complex in the Dabie orogenic belt, Central-Eastern China. All but one eclogite away from veins (EAVs) display nearly constant Nb/Ta ratios ranging from 16.1 to 19.2, with an average of 16.9 ± 0.8 (2 SE), similar to that of their gabbroic protolith from the Yangtze Block. Nb/Ta ratios of rutile from the EAVs range from 12.7 to 25.3 among different individual grains, with the average values close to those of the corresponding bulk rocks. These observations show that Nb and Ta were not significantly fractionated by prograde metamorphism up to eclogite facies when no significant fluid-rock interaction occurs. In contrast, Nb/Ta ratios of rutile from eclogites close to veins (ECVs) are highly variable from 17.8 to 49.8, which are systematically higher (by up to 17) than those of rutile from the veins. These observations demonstrate that Nb and Ta were mobilized and fractionated during localized fluid flow and intensive fluid-rock interaction. This is strongly supported by Nb/Ta zoning patterns in single rutile grains revealed by in situ LA-ICP-MS analysis. Ratios of Nb/Ta in the ECV-hosted rutile decrease gradually from cores towards rims, whereas those in the EAV-hosted rutile are nearly invariable. Furthermore, the vein rutile shows Nb/Ta zoning patterns that are complementary to those in rutile from their immediate hosts (ECVs), suggesting an internal origin for the vein-forming fluids. The Nb/Ta ratios of such fluids evolved from low values at the early stage of subduction to higher values at later supercritical conditions with increased temperature and pressure. Quantitative modelling was conducted to constrain the compositional evolution of metamorphic fluids during dehydration and fluid-rock interaction focusing on Nb–Ta distribution. The modelling results based on our proposed multistage fluid phase evolution path can essentially reproduce the natural observations reported in the present study.

Description: Migmatites are predominant in the North Qinling orogen. However, the formation ages of the migmatites are poorly constrained. This paper presents a combined study of CL image, U-Pb age, trace element, and Hf isotope of zircon in migmatites from the North Qinling unit. In the migmatites, most zircon grains occur as new, homogeneous crystals, while some are present as overgrowth rims around inherited cores. Morphological and trace element features suggest that the zircon crystals are metamorphic and formed during partial melting. The inherited cores have oscillatory zoning and yield U-Pb ages of c . 900 Ma, representing their protolith ages. The early Neoproterozoic protoliths probably formed in an active continental margin, being a response to the assembly of the supercontinent Rodinia. The migmatite zircon yields Hf model ages of 1911 ± 20 to 990 ± 22 Ma, indicating the protoliths were derived from reworking of Paleoproterozoic to Neoproterozoic crustal materials. The anatexis zircon yields formation ages ranging from 455 ± 5 to 420 ± 4 Ma, with a peak at c . 435 Ma. Combined with previous results, we suggest that the migmatization of the NQ terrane occurred at c . 455 to 400 Ma. The migmatization was about 50 Ma later than the c . 490 Ma ultra-high pressure metamorphism, indicating that they occurred in two independent tectonic events. By contrast, the migmatization was coeval with the granulite-facies metamorphism and the granitic magmatism in the North Qinling unit, which collectively argue for their formation due to the northward subduction of the Shangdan Ocean. Ultra-high pressure rocks were distributed mainly along the northern margin and occasionally in the inner part of the North Qinling unit, indicating that they were exhumed along the northern edge and detached from the basement by the subsequent migmatization process. This article is protected by copyright. All rights reserved.

Description: Abstract The evolution of planetary boundary‐layer (PBL) was investigated using observations from laser ceilometer, eddy covariance system and automatic meteorological station in the north of Nanjing city during an air pollution episode in 2016‐2017 winter. Based on 7‐day observation under clean to polluted day, we recorded the temporal variations of backscatter signals observed by the ceilometer, and then inter‐compare planetary boundary‐layer height (PBLH) retrieved from individual methods. The results show that backscatter signal gradient, standard deviation, and wavelet transform analysis methods generated similar PBLH values and PBL diurnal variation patterns. Moreover, the PBL structure varied diurnally, with distinct patterns corresponding to clean and polluted days. Based on these measurements, the relationships between PBLH, weather conditions, and contaminants were analyzed. Results show that: on clean days, strong surface turbulence exchange makes the PBL fully developed and makes the PBLH increased sharply after sunrise, with a maximum of 1483 m; on polluted days, stable synoptic conditions and the weaker wind speeds facilitated the accumulation of air pollutants, leading to smaller net surface radiation and weaker turbulence. Consequently, these conditions during polluted days led to lower PBLH values, which were typically less than 900 m.

Description: In China, cumulative changes in climate and land use/land cover (LULC) from 1981 to 2000 had collectively affected the net productivity in the terrestrial ecosystem and thus the net carbon flux, both of which are intimately linked with the global carbon cycle. This paper represents the first national effort of its kind to systematically investigate the impact of changes of LULC on carbon cycle with high-resolution dynamic LULC data at the decadal scale (1990s and 2000s). The CEVSA was applied and driven by high resolution LULC data retrieved from remote sensing and climate data collected from two ground-based meteorological stations. In particular, it allowed us to simulate carbon fluxes (net primary productivity (NPP), vegetation carbon (VEGC) storage, soil carbon (SOC) storage, heterotrophic respiration (HR), and net ecosystem productivity (NEP)) and carbon storage from 1981 to 2000. Simulations generally agree with output from other models and results from bookkeeping approach. Based on these simulations, temporal and spatial variations in carbon storage and fluxes in China may be confirmed and we are able to relate these variations to climate variability during this period for detailed analyses to show influences of the LULC and environmental controls on NPP, NEP, HR, SOC, and VEGC. Overall, the increases in NPP were greater than HR in most of the time due to the effect of global warming with more precipitation in China from 1981 to 2000. With this trend, the NEP remained positive during that period, resulting in the net increase of total amount of carbon being stored by about 0.296 Pg C within the 20-years time frame. Because the climate effect was much greater than that of changes of LULC, the total carbon storage in China actually increased by about 0.17 Pg C within the 20 years. Such findings will contribute to the generation of control policies of carbon emissions under global climate change.

Description: Evapotranspiration (ET) may be used as an ecological indicator to address the ecosystem complexity. The accurate measurement of ET is of great significance for studying environmental sustainability, global climate changes, and biodiversity. Remote sensing technologies are capable of monitoring both energy and water fluxes on the surface of the Earth. With this advancement, existing models, such as SEBAL, S_SEBI and SEBS, enable us to estimate the regional ET with limited temporal and spatial coverage in the study areas. This paper extends the existing modeling efforts with the inclusion of new components for ET estimation at different temporal and spatial scales under heterogeneous terrain with varying elevations, slopes and aspects. Following a coupled remote sensing and surface energy balance approach, this study emphasizes the structure and function of the Surface Energy Balance with Topography Algorithm (SEBTA). With the aid of the elevation and landscape information, such as slope and aspect parameters derived from the digital elevation model (DEM), and the vegetation cover derived from satellite images, the SEBTA can account for the dynamic impacts of heterogeneous terrain and changing land cover with some varying kinetic parameters (i.e., roughness and zero-plane displacement). Besides, the dry and wet pixels can be recognized automatically and dynamically in image processing thereby making the SEBTA more sensitive to derive the sensible heat flux for ET estimation. To prove the application potential, the SEBTA was carried out to present the robust estimates of 24 h solar radiation over time, which leads to the smooth simulation of the ET over seasons in northern China where the regional climate and vegetation cover in different seasons compound the ET calculations. The SEBTA was validated by the measured data at the ground level. During validation, it shows that the consistency index reached 0.92 and the correlation coefficient was 0.87.

Description: In order to examine energy partitioning and CO2 exchange over a steppe prairie in Inner Mongolia, China, fluxes of moisture, heat and CO2 in the surface layer from June 2007 through June 2008 were calculated using the eddy covariance method. The study site was homogenous and approximately 1500 m×1500 m in size. Seasonal and diurnal variations in radiation components, energy components and CO2 fluxes are examined. Results show that all four radiation components changed seasonally, resulting in a seasonal variation in net radiation. The radiation components also changed diurnally. Winter surface albedo was higher than summer surface albedo because during winter the snow-covered surface increased the surface albedo. The seasonal variations in both sensible heat and CO2 fluxes were stronger than those of latent heat and soil heat fluxes. Sensible heat flux was the main consumer of available energy for the entire experimental period. The energy imbalance problem was encountered and the causes are analyzed.

Description: In order to examine energy partitioning and CO2 exchange over a steppe prairie in Inner Mongolia, China, fluxes of moisture, heat and CO2 in the surface layer from June 2007 through June 2008 were calculated using the eddy covariance method. The study site was homogenous and approximately 1500 m×1500 m in size. Seasonal and diurnal variations in radiation components, energy components and CO2 fluxes are examined. Results show that all four radiation components changed seasonally, resulting in a seasonal variation in net radiation. The radiation components also changed diurnally. Winter surface albedo was higher than summer surface albedo because during winter the snow-covered surface increased the surface albedo. The seasonal variations in both sensible heat and CO2 fluxes were stronger than those of latent heat and soil heat fluxes. This implies that both sensible heat and CO2 fluxes may be more significant climate signals than latent heat and soil fluxes. Sensible heat flux was the main consumer of available energy for the entire experimental period. The energy imbalance problem was encountered and the causes are analyzed.