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    NATURE PUBLISHING GROUP
    In:  EPIC3Nature Geoscience, NATURE PUBLISHING GROUP, 6(10), pp. 885-890, ISSN: 1752-0894
    Publication Date: 2019-07-17
    Description: During the last glacial cycle, greenhouse gas concentrations fluctuated on decadal and longer timescales. Concentrations of methane, as measured in polar ice cores, show a close connection with Northern Hemisphere temperature variability, but the contribution of the various methane sources and sinks to changes in concentration is still a matter of debate. Here we assess changes in methane cycling over the past 160,000 years by measurements of the carbon isotopic composition δ13C of methane in Antarctic ice cores from Dronning Maud Land and Vostok. We find that variations in the δ13C of methane are not generally correlated with changes in atmospheric methane concentration, but instead more closely correlated to atmospheric CO2 concentrations. We interpret this to reflect a climatic and CO2-related control on the isotopic signature of methane source material, such as ecosystem shifts in the seasonally inundated tropical wetlands that produce methane. In contrast, relatively stable δ13C values occurred during intervals of large changes in the atmospheric loading of methane. We suggest that most methane sources—most notably tropical wetlands—must have responded simultaneously to climate changes across these periods.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 2
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    COPERNICUS GESELLSCHAFT MBH
    In:  EPIC3Earth System Science Data, COPERNICUS GESELLSCHAFT MBH, 9(1), pp. 363-387, ISSN: 1866-3516
    Publication Date: 2017-06-21
    Description: Continuous records of the atmospheric greenhouse gases (GHGs) CO2, CH4, and N2O are necessary input data for transient climate simulations, and their associated radiative forcing represents important components in analyses of climate sensitivity and feedbacks. Since the available data from ice cores are discontinuous and partly ambiguous, a well-documented decision process during data compilation followed by some interpolating post-processing is necessary to obtain those desired time series. Here, we document our best possible data compilation of published ice core records and recent measurements on firn air and atmospheric samples spanning the interval from the penultimate glacial maximum ( ∼  156 kyr BP) to the beginning of the year 2016 CE. We use the most recent age scales for the ice core data and apply a smoothing spline method to translate the discrete and irregularly spaced data points into continuous time series. These splines are then used to compute the radiative forcing for each GHG using well-established, simple formulations. We compile only a Southern Hemisphere record of CH4 and discuss how much larger a Northern Hemisphere or global CH4 record might have been due to its interpolar difference. The uncertainties of the individual data points are considered in the spline procedure. Based on the given data resolution, time-dependent cutoff periods of the spline, defining the degree of smoothing, are prescribed, ranging from 5000 years for the less resolved older parts of the records to 4 years for the densely sampled recent years. The computed splines seamlessly describe the GHG evolution on orbital and millennial timescales for glacial and glacial–interglacial variations and on centennial and decadal timescales for anthropogenic times. Data connected with this paper, including raw data and final splines, are available at doi:10.1594/PANGAEA.871273.
    Repository Name: EPIC Alfred Wegener Institut
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  • 3
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    COPERNICUS GESELLSCHAFT MBH
    In:  EPIC3Atmospheric Measurement Techniques, COPERNICUS GESELLSCHAFT MBH, 4, pp. 1445-1461, ISSN: 1867-1381
    Publication Date: 2019-07-17
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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