ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Wiley-Blackwell  (11)
  • American Institute of Physics  (3)
  • American Physical Society (APS)  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 932-939 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The volumetric flow rate of liquid and gas through small gigaporous particles was measured by a new method that isolates single particles in a test apparatus. To our knowledge, this is the first direct confirmation of flow through gigaporous particles made at pressure drops experienced during normal operation. High-performance liquid chromatography particles from 30 to 50 μm in diameter, previously reported to exhibit convection-enhanced intraparticle mass transfer, were studied. Using a CFD model of the test system, the permeability of individual particles was determined from the pressure-drop-flow-rate relationship. The average measured permeability of the particles studied is 7.89 × 10-15 m2 with no dependence on particle size. This is 4 to 17 times greater than values calculated from models currently used to estimate the permeability of these kinds of particles. No other experimentally measured values of permeability have been reported for particles of this size. The results of this study might imply that the intraparticle structure does not behave like a bed of uniformly packed microspheres, but rather as an inhomogeneous assemblage of microparticles. The measured permeability values offer the possibility of developing better models of the intraparticle flow field under normal operating conditions. Knowledge of the intraparticle flow field is an important step in deriving predictive models of convective mass transfer in these types of particles.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 781-787 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    ISSN: 0899-0042
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An enantioselective assay has been developed for the determination of the enantiomers of ketorolac and its metabolite p-hydroxyketorolac in plasma and urine. The analytical method utilizes a coupled achiral-chiral HPLC system where the initial separation of ketorolac from p-hydroxyketorolac and matrix interferences was achieved on a C18-stationary phase and the enantioselective separations of the two target solutes were accomplished on a human serum albumin-based chiral stationary phase. The two columns were attached in sequence and the assay was carried out without the necessity of column-switching techniques. The method has been validated for use in pharmacokinetic and metabolic studies and represents the initial report of the determination of ketorolac and p-hydroxyketorolac enantiomers in urine. The results of the study indicate that after the administration of racemic ketorolac there was an enantioselective distribution of ketorolac enantiomers in plasma [(R)-ketorolac: (S)-ketorolac = 3.89 ± 0.93 (n = 6) and urine (R)-ketorolac: (S)-ketorolac = 1.26 ± 0.09 (n = 7)]. The mean ratio of the p-hydroxyketorolac enantiomers was 1.77 ± 0.46 (n = 7). Both ketorolac and p-hydroxyketorolac are glucuronized in the acyl carboxyl moiety and the results of this study indicate that this process is not enantiospecific. © 1994 Wiley-Liss, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    ISSN: 0899-0042
    Keywords: enantioselective tissue sequestration ; hydroxychloroquine stereoisomers ; cornea ; iris ; retina ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The disposition of the enantiomers of hydroxychloroquine (HCQ) and its major metabolites in ocular tissues of rabbits has been studied. Both albino, New Zealand White (NZW), and pigmented animals were administered daily oral doses of rac-HCQ, (S)-HCQ or (R)-HCQ (20 mg/kg) over 1, 6, or 8 day periods or for 8 days followed by a 7-day washout period. At the end of the study periods, plasma and whole blood samples were collected and the rabbits were sacrificed. The eyes were collected, the aqueous humor removed with a syringe, and the eyes separated into the cornea, lens, vitreous body, iris, choroid-retina, sclera, and conjunctiva. The concentrations of (R)-HCQ, (S)-HCQ, and their respective metabolites were determined using a validated enantioselective liquid chromatographic assay. The data from these studies indicate that HCQ accumulated in both pigmented and nonpigmented ocular tissues. In the pigmented tissues, HCQ and its metabolites were bound to melanin and the binding was not enantiospecific. In the nonpigmented tissues and in the iris and retina-choroid of the NZW rabbits, the accumulation appeared to be the result of a reversible and enantioselective binding of HCQ and its metabolites to an unidentified biopolymer present in these ocular tissues. © 1994 Wiley-liss, Inc.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 35-41 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effective scattering and absorption cross sections were determined from measurements of radiant transmission through isothermal beds of glass, aluminum oxide, steel and silicon carbide spheres, cylinders, and irregular grains. The radiant conductivities were calculated from these cross sections. Back scattering was found to be the principal mechanism of attenuation for all of the packings. Absorption was a significant mechanism only for the silicon carbide grains. At 2,000°F. The radiant contribution to the total heat flux was estimated to vary from 35% for the silicon carbide packings to 85% for the glass packings.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 454-461 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Over 1000 sets of data for forced convective boiling of distilled water, ethylene glycol and aqueous mixtures of ethylene glycol are reported. Most of these data were taken in the annular flow regime. These data indicate a previously unrecognized Prandtl number effect on the boiling heat transfer for both pure components and mixtures. A significant reduction in the heat transfer coefficient is observed for mixtures attributable to mass transfer effects. An expression is developed which accounts for both of these effects and correlates the experimental data to within a mean deviation of 14.9%. This correlation reduces to the standard Chen correlation for pure fluids with Prandtl numbers close to unity.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 544-550 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat transfer from a vertical tube in fluidized beds was investigated by measurement of emulsion packet residence times. The root-square-mean residence times were then used in a modified packet model to successfully predict effective heat transfer coefficients.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 253-259 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The problem of coupled radiation and convection to a medium in slug flow between infinite, parallel plates was formulated in terms of discrete fluxes. Steady state, uniform heat input, and gray boundaries were assumed. The effects of absorption, emission, scuttering, and flow were taken into account. For the general case where all these effects are present, it was necessary to approximate the fourth-order temperature term by a truncated Taylor series. This approximation was not necessary for the special case where conductivity of the medium is negligible.Approximate, analytical solutions in closed form for profiles of temperature, radiant fluxes, and heat fluxes were obtained for both the special case and the general case. Sample results are presented, showing the effects of convection, absolute temperature, absorption coefficient, scattering coefficient, and wall emissivities. The two cases of equal wall temperatures and unequal wall temperatures were both examined.It was found that for a medium with properties approximately representative of those for air carrying a suspension of dust or mist, radiation can account for 60 to 95% of total heat transfer in the temperature range of 900° to 2,800°R. It was also found that for some situations the scattering phenomenon can have a much greater effect on heat transfer than the absorption and emission phenomena.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 1145-1148 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 1127-1131 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The purpose of this study was to determine the two-dimensional temperature field for a fluid in slug flow through tubes with uniform mass injection and linearly decreasing wall temperature. A series solution was obtained, the first ten eigenvalues for which were determined from the characteristic equation by the method of Runge-Kutta. Expressions for local conductive heat flux at the tube wall and local Nusselt number were obtained as a function of inlet Peclet number, injection Peclet number, tube radius, temperature boundary conditions, and fluid properties. Sample results are presented for several injection rates at different wall temperature conditions. In general, mass injection was found to decrease the local heat flux and increase temperature driving force causing a decrease in the Nusselt number.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...