ISSN:
0449-2951
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
This paper describes some of the aspects of the thermal oxidation of deuterated isotactic polypropylenes. Several polymers of propylene, deuterated at different sites along the polymer chain, were subjected to a kinetic treatment designed to establish the comparative rates of oxidation at different temperatures. Infrared spectroscopy was used to follow the kinetics over the temperature interval 100-130°C. These experiments have shown the existence of a deuterium isotope effect for the thermal oxidation of polypropylene.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1965.100030205
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