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  • 1975-1979  (5)
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  • 1
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Linear and branched polyethylene were fractionated by solvent gradient chromatography. The fractions were characterized by light scattering and viscosity measurements. The relationship between the molecular weight and the limiting viscosity number and that between the molecular weight and the radius of gyration in α-chloronaphthaline at 127°C were determined. The exponent of the equation \documentclass{article}\pagestyle{empty}\begin{document}$$\left\langle {g_\eta } \right\rangle _\Theta = \left\langle {g_r } \right\rangle _{\Theta,w}^{\sigma _\Theta } $$\end{document} between the ratio 〈gη〉Θ of the limiting viscosity numbers of branched and linear fractions of the same molecular weight Mw and the corresponding ratio 〈gη〉Θ,w of the radii of gyration for Θ-conditions was \documentclass{article}\pagestyle{empty}\begin{document}$$\sigma _\Theta = 1,2 \pm 0,2$$\end{document}By this equation, the long chain branching of high pressure polyethylene can be determined from 〈gη〉, the ratio of the limiting viscosity numbers in thermodynamically good solvents, which is within the experimental limits of error identical to 〈gη〉Θ in a Θ-solvent. Almost independent of the molecular weight, for the branched polyethylene fractions 1,4 long chain branching points per 1000 C-atoms were obtained.
    Notes: Lineares und verzweigtes Polyäthylen wurden durch Lösungsmittel-Gradienten-Chromatographie fraktioniert. Die Fraktionen wurden durch Streulicht- und Viskositätsmessungen charakterisiert und die Beziehungen zwischen Molekulargewicht und Viskositätszahl bzw. Trägheitsradius in α-Chlornaphthalin bei 127°Cermittelt. Der Exponent in der Beziehung \documentclass{article}\pagestyle{empty}\begin{document}$$\left\langle {g_\eta } \right\rangle _\Theta = \left\langle {g_r } \right\rangle _{\Theta,w}^{\sigma _\Theta } $$\end{document} zwischen dem Verhältnis 〈gη〉Θ der Viskositätszahlen von verzweigten und linearen Fraktionen gleichen Molekulargewichts Mw und dem entsprechenden Verhältnis 〈gη〉Θ,w der Trägheitsradien für Θ-Bedingungen ergab sich zu \documentclass{article}\pagestyle{empty}\begin{document}$$\sigma _\Theta = 1,2 \pm 0,2$$\end{document}Durch diese Gleichung kann die Langkettenverzweigung von Hochdruckpolyäthylen aus dem in thermodynamisch guten Lösungsmitteln bestimmten Viskositätszahlverhältnis 〈gη〉, das mit dem im Θ-Lösungsmittel bestimmten 〈gη〉Θ im Rahmen der Meßgenauigkeit übereinstimmt, ermittelt werden. Für die untersuchten verzweigten Polyäthylen-Fraktionen ergaben sich nahezu unabhängig vom Molekulargewicht etwa 1,4 Langkettenverzweigungen pro 1000 C-Atome.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 43 (1975), S. 167-175 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Limiting viscosity numbers of copolymers of α-methylstyrene and acrylonitrile with acrylonitrile-contents of 30 wt-% were measured in dimethylformamide. The weight average molecular weights (1.6·104 g/mol ≲ Mw ≲ 1.3·106 g/mol) were determined by light scattering. The obtained viscosity-molecular weight relationship is $$\left[ \text{\eta } \right] = 1.25 \cdot 10^{ - 2} \frac{{\text{ml}}}{\text{g}}\left( {\frac{{\text{M}_\text{w} }}{{\text{g/mol}}}} \right)^{0,75}$$ The number average molecular weights were determined by osmotic pressure measurements and the molecular weight heterogeneities were calculated. The homogeneity in chemical composition was investigated by light scattering measurements in different solvents.
    Notes: Für eine Reihe von α-Methylstyrol/Acrylnitril-Copolymerisaten mit einem Acrylnitrilanteil von ca. 30 Gew.-% und Molekulargewichten zwischen 1,6 · 104 und 1,3 · 106 g/mol wurde die Grenzviskosität in Dimethylformamid und das Gewichtsmittel des Molekulargewichts nach der Streulichtmethode bestimmt. Die daraus erhaltene Grenzviskositäts-Molekulargewichtsbeziehung lautet: $$\left[ \text{\eta } \right] = 1.25 \cdot 10^{ - 2} \frac{{\text{ml}}}{\text{g}}\left( {\frac{{\text{M}_\text{w} }}{{\text{g/mol}}}} \right)^{0,75}$$ Mit Hilfe osmotischer Messungen wurde noch das Zahlenmittel des Molekulargewichts bestimmt und die Molekulargewichtsuneinheitlichkeit der Proben berechnet. Außerdem wurde durch Streulichtmessungen in verschiedenen Lösungsmitteln die Einheitlichkeit im chemischen Aufbau der Makromolekeln geprüft.
    Additional Material: 3 Tab.
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  • 3
    Publication Date: 2022-07-21
    Description: Samples from surface sediments of the shelf, continental slope, and adjacent deep sea regions off West Africa between 27° N and 15° N were investigated with respect to grain size distribution of the total samples, sand contents of the acid insoluble residues, carbonate content of the total samples, and the separate grain size fractions, specific surfaces, colours and mineralogical composition of the clay fractions. The grain size distributions of the total samples of the sediments of the shelf and the continental slope off Spanish-Sahara are controlled mainly by biogenic components. The supply of terrigeneous material in this area is very low. At deeper parts of the continental slope and in the deep sea areas, the relative amounts of carbonate minerals in the sediments are considerably reduced. The prevailing sand contents of the upper slope changes into clay dominance. On the shelf off Mauritania - represented by profiles extending down to 200 m of water depth - the grain size is also controlled mainly by biogenic carbonates. Nevertheless, the admixture of fossil silicate components is important, too. The southern parts of the area investigated are located in a region influenced by sediments of the Senegal River, which especially control the contents of silt and clay. The silicate sands, predominatcly of quartz, are fossil and form a mixed sediment with younger deposits. The carbonate contents of the different grain size fractions are formed either by sedimentation of carbonate and silicate particles of the respective grain sizes or by autochtonous disintegration of coarser sediment particles, as shown by the occurrence of Mg-rich calcite and especially aragonite in the clay sized fractions. In the northern parts of the area investigated, which have very minute terrigeneous supply, the latter mechanism is the dominant factor, controlling the carbonate contents of the fine grain sized fractions. In the vicinity of the mouth of the Senegal the carbonate contents are influenced by extremely high dilution with terrigeneous silicates. Mg-rich calcite and aragonite are produced preferentially in shallow slope and shelf areas up to 500 m of watet depth. The spccific surfaces of the carbonate-frce clay fractions indicate that the clay fractions of the shelf areas with little terrigeneous supply consist of relatively coarse particles. Very fine particles are removed and transported towards the deep sea. Lateral differentiation of this kind was not observed in the area off Senegal. The high surface areas, characterizing the clay fractions of this region, are thought to be due to high montmorillonite contents as was also found for deep sea sediments. The mineralogical composition of the clay fractions from the southern parts of the area is characterized by high kaolinite and montmorillonite contents, while in the north illite is predominating. At least two types of montmorillonites are present: in areas influenced by the Senegal mostly one type was found, which could swell to 17 A; on the shelves and slopes of the other regions the montmorillonitegroup is represented by a montmorillonite-micatype mixed-layer mineral. A "glauconite", found in the sand fractions, which bad very similar properties to those of the montmorillonite-mica mixed-layer, is believed to be the source of this mixed-layer-type mineral. Palygorskite is present in all samples out of range of the Senegal supply. lt may be an indicator of eolian transported material. The occurrence of rich palygorskit deposits in the arid hinterlands emphasizes the terrestrial origin.
    Type: Article , PeerReviewed
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  • 4
    Publication Date: 2022-07-22
    Description: Sediment cores from the continental slope off NW Africa (20-27° N) have been investigated by means of an analysis of clay minerals, of grajn size distribution of terrigenous material and of coarse fractions and CaC03 -contents. Deductions concerning Late Quaternary climatic variations could be made from the obtained results. The interglacial periods X and Z (stage 1 and 5 after SHACKLETON & OPDYKE 1973) had an arid climate, characterized by: a) presence of chlorite and attapulgite in noticeable amounts, these fragile minerals being preserved from weathering in dry climatic conditions, b) small grain size of terrigenous material, c) high desert quartz numbers, high CaC03-amounts of total sediment, small terrigenous input and low transport energy. The glacial periods Y and W (stage 2-4 and 6) had a humid climate. This is suggested by: a) the absence or rareness of chlorite and attapulgite and increasing amounts of mixed-layer minerals, b) high amounts of coarse-grained terrigenous material, indicating greater transport energy, c) low or disappearing desert quartz numbers, low CaC03-content and high terrigenous input. The cores from 27 and 20° N do not fit into this general scheme, because they are situated at climatic boundaries, the northern core lying at the actual boundary of mediterranean humid and arid climate, the southern core lying at the Würm boundary between humid and arid climate. Results of 40-63 μm sized desert quartz and amount of 〈6 respectively 20-63 μm fraction show sharp boundaries between stratigraphic zones, revealing rapid changes in climate. Clay mineralogical changes are less rapid, showing the progressive changes in soil formation and soil destruction. The origin of the clay minerals is exclusively detrital. Their quantitative variations show a differential settling with distance from coast, and a latitudinal zonation parallel to terrestrial soils.
    Type: Article , PeerReviewed
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  • 5
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    Unknown
    PANGAEA
    In:  Supplement to: Lange, Heinz (1975): Herkunft und Verteilung von Oberflächensedimenten des westafrikanischen Schelfs und Kontinentalhanges. Meteor Forschungsergebnisse, Deutsche Forschungsgemeinschaft, Reihe C Geologie und Geophysik, Gebrüder Bornträger, Berlin, Stuttgart, C22, 61-84
    Publication Date: 2024-02-03
    Description: Samples from sutface sediments of the shell, continental slope, and adjacent deep sea regions off West Africa between 27° N and 15° N were investigated with respect to grain size distribution of the total samples, sand contents of the acid insoluble residues, carbonate content of the total samples, and the separate grain size fractions, specific surfaces, colours and mineralogical composition of the clay fractions. The grain size distributions of the total samples of the sediments of the shelf and the continental slope off Spanish-Sahara are controlled mainly by biogenic components. The supply of terrigeneous material in this area is very low. At deeper parts of the continental slope and in the deep sea areas, the relative amounts of carbonate minerals in the sediments are considerably reduced. The prevailing sand contents of the upper slope changes into clay dominance. On the shelf of Mauritania – represented by profiles extending down to 200 m water depth – the grain size is also controlled mainly by biogenic carbonates. Nevertheless, the admixture of fossil silicate components is important, too. The southern parts of the area is investigated are located in a region influenced by sediments of the Senegal River, which especially control the contents of silt and clay. The silicate sands, predominately of quartz, are fossil and form a mixed sediment with younger deposits. The carbonate contents of the different grain size fractions are formed either by sedimentation of carbonate and silicate particles of the respective grain size or by autochtonous disintegration of coarser sediment particles, as shown by the occurence of Mg-rich calcite and especially aragonite in the clay sized fraction. In the northern parts of the area investigated, which have very minute terrigeneous supply, the latter mechanism is the dominant factor, controlling the carbonate contents of the fine grain sized fractions. In the vicinity of the mouth of the Senegal the carbonate contents are influenced by extremely high dilution with terrigencous silicates. Mg-rich calcite and aragonite are produced preferentially in shallow slope and shelf areas up to 500 m of water depth. The specific surfaces of the carbonate-free clay fractions indicate that the clay fractions of the shelfareas with little terrigenous supply consits of relatively coarser particles. Very fine particles are removed and transported towards the deep sea. Lateral differentiation of this kind was not observed in the area off Senegal. The high surface areas, characterizing the clay fractions of this region, are thought to be due to high montmorillonite contents as was found for deep seas sediments. The mineralogical composition of the clay fraction from the southern parts of the area is characterized by high kaolinite and montmorillonite contents, while in the northern illite is predominating. At least two types of montmorillionites are present: in areas influenced by the Senegal mostly one type was found, which could swell to 17; on the shelves and slopes of the other regions the montmorillonite-group is represented by a montmorillonite-mica-type mixed-layer mineral. A “glauconite”, found in the sand fraction, which had very similar properties to those of the montmorillonite-mica mixed-layer, is believed to be the source of this mixed-layer-type mineral. Palygorskite is present in all samples out of range of the Senegal supply. It may be an indicator of eolian transported material. The occurence of rich palygorskit deposits in the arid hinterlands emphasizes the terrestrial origin.
    Keywords: Bottle, Niskin; Carbonates; DEPTH, sediment/rock; East Atlantic; Elevation of event; Event label; FBG; GIK/IfG; GIK12301-4; GIK12302-3; GIK12303-2; GIK12304-2; GIK12305-2; GIK12306-2; GIK12307-3; GIK12308-2; GIK12309-1; GIK12310-1; GIK12311-1; GIK12312-2; GIK12313-2; GIK12314-1; GIK12315-1; GIK12316-1; GIK12317-1; GIK12318-1; GIK12319-1; GIK12320-1; GIK12321-1; GIK12322-2; GIK12323-1; GIK12324-1; GIK12325-2; GIK12326-3; GIK12327-2; GIK12328-1; GIK12329-2; GIK12330-1; GIK12331-3; GIK12332-2; GIK12334-2; GIK12335-1; GIK12338-1; GIK12339-2; GIK12340-3; GIK12341-2; GIK12342-1; GIK12343-1; GIK12344-1; GIK12345-3; GIK12346-1; GIK12350-1; GIK12351-1; GIK12352-1; GIK12353-1; GIK12354-1; GIK12355-1; GIK12356-1; GIK12357-1; GIK12358-1; GIK12360-1; GIK12361-1; GIK12362-1; GIK12363-1; GIK12364-1; GIK12365-1; GIK12366-1; GIK12367-1; GIK12368-1; GIK12369-3; GIK12370-1; GIK12371-2; GIK12372-1; GIK12373-1; GIK12374-2; GIK12375-2; GIK12376-2; GIK12377-1; GIK12378-1; GIK12386-1; GIK12387-1; GIK12388-2; GIK12389-1; GIK12390-1; GIK12391-1; Illite (Intensity, 10Å); Inner Area; Institute for Geosciences, Christian Albrechts University, Kiel; Kaolinite+Chlorite (Intensity, 7Å); Latitude of event; Longitude of event; M25; Meteor (1964); NIS; Photo grab; Size fraction 〈 0.002 mm, clay; Size fraction 〉 0.063 mm, sand; Size fraction 0.0063-0.002 mm, fine silt; Size fraction 0.020-0.0063 mm, medium silt; Size fraction 0.063-0.020 mm, coarse silt; Smectite (Intensity, 17Å); van Veen Grab; VGRAB; Vibration corer IOW; VKG
    Type: Dataset
    Format: text/tab-separated-values, 1121 data points
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