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  • 1985-1989  (2)
  • 1965-1969  (15)
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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 759-763 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In this paper a conjecture of Aris is proved to be correct, that of all catalyst particles of fixed volume for isothermal first-order chemical reactions the spherical particle has the lowest effectiveness factor. The method of proof uses a process of symmetrization. Some conjectures are also made about other chemical reactions. The method of proof is also valid for two-dimensional domain (infinite cylinder).
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 194-199 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A shell progressive kinetic model is used to determine the temperature rise in a spherical pellet for a gas-solid diffusion controlled reaction. The effects of heat and mass transfer resistances in the gas film as well as inside the pellet are investigated. The predicted temperature rise may be severe enough to cause sintering to catalyst pellets in which reactions such as combustion of coke occur.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 1202-1211 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The theoretical transient behavior of an isothermal packed bed or tubular reactor with direct recycle is investigated. It is shown that the recycle effect, coupled with the phenomenon of axial dispersion, causes waves in the reactant concentration to travel through the bed when the feed concentration undergoes a step change. The waves have a length almost equal to the bed length and they travel with the velocity of the fluid. The behavior of the waves is very insensitive to the value of the Peclet number.The pertinent linear differential equation is solved by the method of generalized Fourier transforms and the boundary conditions are such that the Sturm-Liouville theorem cannot be used. The operator is nonself-adjoint and the eigenfunctions are not mutually orthogonal. The eigenvalues, which are complex, are found by means of the argument principle. Sample calculations are presented of the first one hundred terms of the Fourier expansion of a solution function and this is compared to a simplified approximate series which is developed.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 211-221 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This work is a study of the stability of a batch fluidized bed with a simple model. It is shown that multiple steady states can occur with all catalyst particles at the same temperature, some of these states being unstable. If the initial temperature of all the particles is not the same, a special kind of steady state, in which particles of different temperatures can coexist in the bed, might be obtained. The number of these pathological steady states is not finite, and the conversion obtained may be very different from that obtained by a uniform steady state.The analysis has demonstrated that the initial temperature of the catalyst particles may be a predominate factor in determining the kind of steady state obtained. For the case of uniform catalyst particles, a simple stability analysis has been developed. Several numerical solutions of the transient equations were performed to investigate the possible responses of the system to disturbances of various steady states.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 339-350 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Three models of a catalyst particle are examined for existence of multiple steady states depending upon whether intraparticle heat conduction or diffusion is important. The particle with constant temperature but with intraparticle diffusion is examined in detail and a necessary and sufficient condition for the stability of the steady state is obtained. Calculations are made for a particle with both intraparticle diffusion and conduction and it is shown that there may be multiple steady states some of which are unstable to small perturbations.
    Additional Material: 20 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 279-290 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method of determining all the possible steady states of a tubular recycle reactor with plug flow is presented. The information needed to determine the steady states can be used to ascertain the asymptotic and global stability of the reactor without performing transient computations. The effects of changes in the recycle ratio and start-up conditions are examined. Several numerical examples are included to demonstrate the use of the method for various types of recycle reactors.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 636-643 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A simple cell model is used for the determination of necessary and sufficient conditions for the stability of an adiabatic fixed bed reactor. These conditions are stronger than those obtained by considering only a perturbation of a single particle. Because of the nonuniqueness of the steady state profiles certain pathological effects can occur when the flow rate of the reactant is changed. Geometric coupling between the particles and heat transfer by radiation give rise to further complexities. Examples are given in which the trends predicted by the models have been observed experimentally by Wicke and Frank-Kamenetskii.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Publication Date: 1989-10-01
    Print ISSN: 0045-7825
    Electronic ISSN: 1879-2138
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Published by Elsevier
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  • 9
    Publication Date: 1968-01-01
    Print ISSN: 0022-0396
    Electronic ISSN: 1090-2732
    Topics: Mathematics
    Published by Elsevier
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  • 10
    Publication Date: 1965-03-01
    Print ISSN: 0001-1541
    Electronic ISSN: 1547-5905
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Published by Wiley on behalf of American Institute of Chemical Engineers.
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