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  • GEOPHYSICS  (3)
  • 1990-1994  (3)
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  • 1990-1994  (3)
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  • 1
    Publication Date: 2011-08-24
    Description: HALOE observations of O3, CH4, HF, H2O, NO, NO2, and HCl collected during the October 1991 Antarctic spring period are reported. The data show a constant CH4 mixing ratio of about 0.25 ppmv for the altitude range from 65 km down to about 25 km at the position of minimum wind speed in the vortex: i.e., the vortex center, and depressions in pressure versus longitude contours of NO, NO2, HF, and HCl in this same region. Water vapor, HF, and HCl enhancement are also observed in the vortex center region above about 25 km. Between 10 and 20 km, the expected mixing ratio signatures exist within the vortex, i.e., low ozone and dehydration. The water vapor increased by 50 percent, and the ozone level doubled inside the vortex between October 11 and 24 in the 15-20 km layer. These changes imply a time constant for recovery from ozone hole conditions of 19 and 30 days for O3 and H2O, respectively. The data further show the presence of air inside the vortex between 3 and 30 mb which has mixing ratios characteristic of midlatitudes.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 20; 8; p. 719-722.
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  • 2
    Publication Date: 2011-08-24
    Description: The Halogen Occultation Experiment (HALOE) uses solar occultation to measure vertical profiles of O3, HCl, HF, CH4, H2O, NO, NO2, aerosol extinction, and temperature versus pressure with an instantaneous vertical field of view of 1.6 km at the earth limb. Latitudinal coverage is from 80 deg S to 80 deg N over the course of 1 year and includes extensive observations of the Antarctic region during spring. The altitude range of the measurements extends from about 15 km to about 60-130 km, depending on channel. Experiment operations have been essentially flawless, and all performance criteria either meet or exceed specifications. Internal data consistency checks, comparisons with correlative measurements, and qualitative comparisons with 1985 atmospheric trace molecule spectroscopy (ATMOS) results are in good agreement. Examples of pressure versus latitude cross sections and a global orthographic projection for the September 21 to October 15, 1992, period show the utility of CH4, HF, and H2O as tracers, the occurrence of dehydration in the Antarctic lower stratosphere, the presence of the water vapor hygropause in the tropics, evidence of Antarctic air in the tropics, the influence of Hadley tropical upwelling, and the first global distribution of HCl, HF, and NO throughout the stratosphere. Nitric oxide measurements extend through the lower thermosphere.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 98; D6; p. 10,777-10,797.
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  • 3
    Publication Date: 2011-08-19
    Description: The effects of dimethyl sulfide (DMS) and methyl iodide (MI) emissions are analyzed using a two-dimensional photochemical model of a marine tropical tropospheric synoptic system. The model traces the atmospheric transformation cycles of the emissions to aerosols. The study is focused on remote tropical ocean regions and includes simulations of the spatial and diurnal variations of various iodine and sulfur species, and the species OH, HO2, and H2O2. One line of analysis leads to the conclusion that the reaction IO + DMS yields DMSO + I may play a significant role in destroying DMS if it proceeds at the published fast rate. Alternative lines of analyses are presented.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 95; 22319-22
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