ISSN:
0009-2940
Keywords:
Bicyclopropyl / Diphosphines, chelating ligands / Rhodium complexes / Gold complexes / Phosphine sulfides / Phosphine-boranes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The title compound 4 has been prepared from readily available 2,3-bis(diphenylphosphinyl)-1,3-butadiene (1) through double cyclopropanation using Me2S(CH2)O to give 1,1′-bis(diphenylphosphinyl)bicyclopropyl (2), followed by reduction using HSiCl3/NEt3. Addition of sulfur to compound 4 yields the disulfide 5, and reaction with tetrahydrofuran - borane affords the 1:2 adduct with BH3 (6). Quaternization reactions with MeI or CH2I2 give the double quaternary salts 7 and 8, respectively. Single dehydrohalogenation employing nBuLi converts 8 into the cyclic semiylide salt 9. 4 is an excellent ligand for lowvalent late transition-metal cations. With PdI2 the 1:1 complex LPdI2 (10, with L = 4), and with [(CO)2RhCl]2 the ionic 2:1 complex L2Rh+Cl- (11) are obtained. Experiments with (CO)AuCl yield the 1:2 complex L(AuCl)2 (12), X-ray structure analyses were performed with single crystals of the disulfide 5, as well as the rhodium(I) and gold(I) complexes 11 and 12. 5 has a conformation between s-cis and s-trans with the PS functions pointing away from each other at opposite ends of the molecule. By contrast, in the gold(I) complex the ligand approaches an s-cis conformation, and through rotations about P-C and C-C bonds - as referred to the conformation of 5 - the metal atoms are brought into close contact: Au…Au = 3.085 Å. Through temperature-dependent NMR investigations of compounds 5 and 12, and by comparison with values calculated or experimentally determined for related bicyclopropyl compounds (available in the literature), the energy of the Au…Au attraction has been estimated to be ca. 6 kcal/mol. Compound 11 features a square-planar, double-chelate cation.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19901230303
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