ISSN:
0009-2940
Keywords:
Borates, triorgano-oxy, potassium salts
;
N-Lewis base - diorgano(silyloxy)boranes
;
Bicyclo[2.2.1]heptanes, heteroatom-containing, diastereomeric
;
P-Lewis base - triorganoboranes, monocyclic, unsaturated
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
OrganosubstitutedBicyclic and Monocyclic Compounds from 2,5-Dihydro-1,2,5-oxasilaboratolates1a)The potassium salts of the cyclic anions of (A: R, R′ = CH3; B: R = C2H5, R′ = CH3; C: R = C6H5, R′ = CH3 react with [(CH3)2NCH2]Br in THF to yield the bicyclic compounds 1a (X-ray crystal structure analysis), 1b/1b' (endo/exo-C2H5), and 1c/1c' (endo/exo-C6H5). D (R=CH3, R'=C6H5) reacts with [(CH)32NCH2]Br to form a 1:4 mixture of 1d together with the heterocycle (3d) with elimination of (CH3)2N-C3H7. - From A - D and CIP(C6H5)2 the six-membered heterocycles (2a-d) are obtained in yields of ca. 90%.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240507
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