ISSN:
1572-879X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Exceptionally high catalytic activities (TOF〉2500 h-1) have been achieved in the biphasic hydrocarboxylation of propene catalysed by water-soluble Pd/TPPTS complexes. The activity was even higher than that exhibited by organic-soluble Pd/PPh3 systems. This contrasts with the general perception that biphasic catalysis normally exhibits lower rates compared to analogous reactions in organic media. The hydrocarboxylation of 4-isobutylstyrene to ibuprofen and of styrene in a two-phase system is also reported.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1019015912635
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