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Transition metal-saccharide chemistry: d-glucose complexes of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) (1995)

Bandwar, Rajiv P. ; Srinivasa Raghavan, M. S. ; Rao, Chebrolu P.

Springer

BioMetals 8 (1995), S. 19-24

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ISSN: 1572-8773

Keywords: Co(II) ; complexes ; Cu(II) ; glucose ; Mn(II) ; Ni(II) ; saccharide ; transition metal ; Zn(II)

Source: Springer Online Journal Archives 1860-2000

Topics: Biology , Chemistry and Pharmacology

Notes: Abstract Metal complexes of d-glucose (d-Glc) from large cation containing dibromo-dichloro salts of dipositive metals [NEt4]2[MBr2Cl2] (M = Mn, Co, Ni, Cu and Zn) and the disodium salt of glucose were synthesized from a MeOH:MeCN mixture. The complexes were characterized by UV-vis absorption, circular dichroism, IR and proton magnetic resonance spectroscopies, and by elemental analysis, and were found to be Na[M(d-Glc)(OMe)Cl]. Cyclic voltammetric studies of these complexes, in the acidic to neutral pH range, indicated no dissociation, even in highly acidic conditions.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00156153

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