ISSN:
1573-4994
Keywords:
Intramolecular energy transfer
;
1-pyrenoate
;
methylene spacers
;
fluorescence anisotropy
;
fluorescence lifetime
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract Steady-state fluorescence anisotropy (r) and fluorescence lifetime (τ) measurements have been used to study the efficiency of nonradiative singlet energy transfer as a function of alkane size in 1-pyrenecarboxylic acid alkanediyl esters (as a function ofm in Py-COO-(CH2) m -OOC-Py, where Py denotes pyrene substituted in the 1-position, andm=2–6). Experiments were performed in media of different viscosity, η, obtained by changing the temperature (from −20 to 40°C) of dilute solutions in ethylene glycol and by examination of the compounds in a solid matrix of poly(methyl methacrylate) (PMMA) at ambient temperature. The Py-COO-(CH2)m-OOC-Py exhibit intramolecular excimer emission in ethylene glycol at these temperatures, but the intensity of this emission is much lower than when these compounds are placed in common solvents of lower η. The values of τ indicate that excitation hopping or intramolecular energy transfer takes place between the chromophores attached to the ends of the alkane bridges. Values ofr obtained by the extrapolationsT/η→0 orτT/η→0 in ethylene glycol, as well as the values obtained in the rigid matrix of PMMA, show very little dependence onm. A theoretical conformational analysis, using the rotational isomeric state (RIS) model, was also performed. The combination of the experimental results forr in the media of high η with the theoretical (RIS) analysis produces an estimated value of 21 ±2 Å for the Förster radius in Py-COO-(CH2)m-OOC-Py.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00726725
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