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  • 2000-2004  (213)
  • 1985-1989  (87)
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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 73 (2002), S. 1235-1241 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We report the combination of a high-pressure sample chamber and a stable, nonscanning, angle-dispersive Fabry–Perot interferometer allowing the rapid measurement of inelastic light scattering from acoustic phonon modes in solid and liquid samples at high pressure. The primary components of the apparatus are a (i) narrow frequency gas ion laser, (ii) a solid or air-spaced etalon, (iii) a multichannel charge coupled device detector, and (iv) a large volume, high-pressure cell. The fundamental principle of this spectrometer is based on the angular dispersion of light through an etalon, whereupon the multiple-order frequency dispersed spectrum can be acquired with an array detector. Typical acquisition times are less than 1 s using low to moderate laser power. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 60 (1989), S. 143-147 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The formulas for accidental coincidence corrections published recently by DeVolpi are found to be in error and, in particular, to conflict with the results of Monte Carlo simulations and with various published exact formulas. It is shown that the traditional first-order approximate formulas are valid both for the conditions assumed by their authors, and also, at low count rates, for the conditions used by DeVolpi.
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 52 (1988), S. 236-238 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We calculate the contribution of polar optic phonons to the inelastic scattering rate for an electron traversing semiconductor heterojunctions. In typical geometries, a dramatic reduction in scattering rate compared to the bulk value is found for a limited range of electron energies. This effect is related to spatial separation of initial and final electron wave functions either side of the heterojunction caused by quantum mechanical reflection at the interface. The influence of this phenomenon on the performance of devices, such as unipolar hot-electron transistors, is discussed.
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 81 (2002), S. 171-173 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A concept to electrically control the scattering of light is introduced. The idea is to embed noble metal nanoparticles in an electro-optical material such as a liquid crystal in order to induce a spectral shift of the particle plasmon resonance by applying an electric field. Light scattering experiments on single gold nanoparticles show that spherically shaped nanoparticles become optically spheroidal when covered by an anisotropic liquid crystal. The two particle plasmon resonances of the optically spheroidal gold nanoparticles can be spectrally shifted by up to 50 meV when electric fields of more than 10 kV/cm are applied. © 2002 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 560 (1989), S. 0 
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 113 (2000), S. 876-882 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Spectral diffusion (SD) in polymethylmethacrylate (PMMA) doped with free-base tetraphenylporphine is investigated at 0.5–4.2 K on a time scale of 3–106 s via optical hole burning. Two contradictory results—within the framework of the two level system (TLS) model—are obtained. The first one is the absence of aging effects at temperatures near 4 K which puts the upper limit for the TLS relaxation times at tens of minutes. The second one is an intensive superlogarithmic SD on the whole time scale of the experiment, which is evidence for the presence of very slow relaxations, independent of the sample history on a time scale of up to two months. The results presented provide clear evidence of a deviation of SD behavior from the TLS model predictions at moderately low temperatures. The concept of structural relaxations is applied for a qualitative interpretation of the experimental data. © 2000 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 18 (1985), S. 241-247 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: Although the quality of a structure model obtained from small-angle X-ray or neutron scattering curves for polymers can be determined qualitatively by comparing the isotropic scattering curve calculated for the model with the experimental scattering data for a solution of polymer molecules, other methods are needed for a more precise evaluation. A model resolution function has been defined to permit quantitative comparisons. With this function, the quality of the approximation can be assessed, and the structure resolution can be determined. An overinterpretation of scattering curves by use of complex but uniform-density models can thus be avoided. Furthermore, the value of the Porod volume calculated from the scattering data has been found to depend strongly on the interval in which the scattering data are recorded or selected for evaluation. The calculations with the atomic model curves showed that it is impossible to compute physically meaningful values of the hydration of the molecules from the Porod volume and the dry volume by use of extrapolated scattering curves with an insufficient resolution. The theory of the model resolution function and the interpretation of the Porod volume have been verified and tested with experimental scattering curves from solutions of RNA molecules.
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  • 8
    ISSN: 1432-0495
    Keywords: Key words East Germany ; Erzgebirge ; Eutrophication ; Heavy metals ; Lake sediments ; Mining ; Pollution development
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract. The Malter Reservoir is situated about 30 km south of Dresden (eastern Germany) in a historical mining area of the eastern Erzgebirge. It was built in 1913 for the protection from floodwaters, droughts and for generating electricity. The river Rote Weißeritz is the main source of clastic input into the lake. Geochemical and sedimentological data of gravity-and piston-cores, recovered from the deepest point of the lake, document the environmental history of the drainage area since 1963. 137Cs dating gives an average sedimentation rate of ∼2.9 cm/year. Within the whole core, heavy metals are strongly enriched (parentheses refer to enrichment factors as compared with average shale): cadmium (290), silver (140), bismuth (90), antimony (25), lead (21), zinc (14), tin (13), uranium (9), tungsten (9), molybdenum (5), copper (4), thallium (3) and chromium (2). Enrichments are detectable for the whole registered time-period of 81 years. Peaks of up to 27 mg/kg silver, 37 mg/kg bismuth, 91 mg/kg cadmium, 410 mg/kg chromium, 240 mg/kg copper, 20 mg/kg molybdenum, 14000 mg/kg phosphorus, 740 mg/kg lead, 6,5 mg/kg antimony, 74 mg/kg tin, 52 mg/kg tungsten and 1900 mg/kg zinc reflect local events caused by human impact. Inputs from different pollution sources at different times are represented by highly variable elemental concentrations and ratios within the core. High pH values within the water and the sediment column, the large adsorption capacity of the fine-grained Corg.-rich sediment, and the presence of low Eh-values and sulphide ions in the sediment prevent the remobilisation of the toxic elements. Erosion of these contaminated sediments during floods, channel flows or resuspension during removal of the sediments may lead to a downstream transfer of pollutants. Contents of P and Corg., as well as diatom abundance, indicate a change from oligotrophic to eutrophic conditions in the lake during ∼1940–1950. This was mainly caused by high agricultural activity in the drainage area. Reduced contents of Cu, Zn, Cd and Cr since the reunification of East and West Germany are obviously caused by increasing environmental protection measures, such as wastewater purification and especially the closing of contaminating industries.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 49 (1989), S. 681-690 
    ISSN: 1432-0630
    Keywords: 73.20Hb
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The potential energy and surface dipole were calculated as a function of the geometry of the coadsorbed systems using the cluster method and theoretical oscillation frequencies and work function changes were compared with experiment. It was found that the K fills unoccupied Pt 5d states and reduces the local polarizability of the metal. The H2O molecule binds to the K atom, such that the H atoms point towards the surface inducing an increase in the work function. For the CO molecule a charge transfer (K→CO) through the surface stabilizes the bond and induces a change of adsorption place (on-top→bridge). The K increases the tendency to H2 dissociation because of the local decrease of the work function. Zero-point energy effects add important dynamical features to the electronic H2- surface interaction. Three examples for the Pt(111)-H2 system are presented: (i) A virtual attractive potential well produced by the softening of the H-H bond near the surface, (ii) a virtual potential barrier for dissociation due to the hindering of molecular rotations at the surface, and (iii) a change in the apparent surface temperature in H2 desorption processes.
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  • 10
    ISSN: 1432-1017
    Keywords: Ribosomal 5S RNA ; structure ; X-ray scattering ; dynamic light scattering
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Physics
    Notes: Abstract The structures of eukaryotic ribosomal 5S RNA from rat liver and of prokaryotic 5S RNA from E. coli (A-conformer) have been investigated by scattering methods. For both molecules, a molar mass of 44,500±4,000 was determined from small angle X-ray scattering as well as from dynamic light scattering. The shape parameters of the two rRNAs, volume V c, surface O c, radius of gyration R s, maximum dimension of the molecule L, thickness D, and cross section radius of gyration R sq, agree within the experimental error limits. The mean values are V c=57±3 nm3, O c=165±10 nm2, R s=3.37±0.05 nm, L=10.8±0.7 nm, D=1.57±0.07 nm, R sa=0.92±0.01 nm. Identical structures for the E. coli 5S rRNA and the rat liver 5S rRNA at a resolution of 1 nm can be deduced from this agreement and from the comparison of experimental X-ray scattering curves and of experimental electron distance distribution function. The flat shape model derived for prokaryotic and eukaryotic 5S rRNA shows a compact region and two protruding arms. Double helical stems are eleven-fold helices with a mean base pair distance of 0.28 nm. Combining the shape information obtained from X-ray scattering with the information about the frictional behaviour of the molecules, deduced from the diffusion coefficients D 20,w 0 =(5.9±0.2)·10-7 cm2s-1 and (6.2±0.2)·10-7 cm2s-1 for rat liver 5S rRNA and E. coli 5S rRNA, respectively, a solvation shell of about 0.3 nm thickness around both molecules is determined. This structural similarity and the consensus secondary structure pattern derived from comparative sequence analyses suggest that all 5S rRNAs may indeed have conserved essentially the same type of folding of their polynucleotide strands during evolution, despite having very different sequences.
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