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  • 2000-2004  (8)
  • 1990-1994  (6)
  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    Sedimentology 51 (2004), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Two types of ‘pseudobreccia’, one with grey and the other with brown mottle fabrics, occur in shoaling-upward cycles of the Urswick Limestone Formation of Asbian (Late Dinantian, Carboniferous) age in the southern Lake District, UK. The grey mottle pseudobreccia occurs in cycle-base packstones and developed after backfilling and abandonment of Thalassinoides burrow systems. Burrow infills consist of a fine to coarse crystalline microspar that has dull brown to moderate orange colours under cathodoluminescence. Mottling formed when an early diagenetic ‘aerobic decay clock’ operating on buried organic material was stopped, and sediment entered the sulphate reduction zone. This probably occurred during progradation of grainstone shoal facies, after which there was initial exposure to meteoric water. Microspar calcites then formed rapidly as a result of aragonite stabilization. The precipitation of the main meteoric cements and aragonite bioclast dissolution post-date this stabilisation event. The brown mottle pseudobreccia fabrics are intimately associated with rhizocretions and calcrete, which developed beneath palaeokarstic surfaces capping cycle-top grainstones and post-date all depositional fabrics, although they may also follow primary depositional heterogeneities such as burrows. They consist of coarse, inclusion-rich, microspar calcites that are always very dull to non-luminescent under cathodoluminescence, sometimes with some thin bright zones. These are interpreted as capillary rise and pedogenic calcrete precipitates. The δ18O values (−5‰ to −8‰, PDB) and the δ13C values (+2‰ to −3‰, PDB) of the ‘pseudobreccias’ are lower than the estimated δ18O values (−3‰ to −1‰ PDB) and δ13C values of (+2‰ to +4‰ PDB) of normal marine calcite precipitated from Late Dinantian sea water, reflecting the influence of meteoric waters and the input of organic carbon.
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    Sedimentology 51 (2004), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Pervasive dolomites occur preferentially in the stromatoporoid biostromal (or reefal) facies in the basal Devonian (Givetian) carbonate rocks in the Guilin area, South China. The amount of dolomites, however, decreases sharply in the overlying Frasnian carbonate rocks. Dolostones are dominated by replacement dolomites with minor dolomite cements. Replacement dolomites include: (1) fine to medium, planar-e floating dolomite rhombs (Rd1); (2) medium to coarse, planar-s patchy/mosaic dolomites (Rd2); and (3) medium to very coarse non-planar anhedral mosaic dolomites (Rd3). They post-date early submarine cements and overlap with stylolites. Two types of dolomite cements were identified: planar coarse euhedral dolomite cements (Cd1) and non-planar (saddle) dolomite cements (Cd2); they post-date replacement dolomites and predate late-stage calcite cements that line mouldic vugs and fractures. The replacement dolomites have δ18O values from −13·7 to −9·7‰ VPDB, δ13C values from −2·7 to + 1·5‰ VPDB and 87Sr/86Sr ratios from 0·7082 to 0·7114. Fluid inclusion data of Rd3 dolomites yield homogenization temperatures (Th) of 136–149 °C and salinities of 7·2–11·2 wt% NaCl equivalent. These data suggest that the replacive dolomitization could have occurred from slightly modified sea water and/or saline basinal fluids at relatively high temperatures, probably related to hydrothermal activities during the latest Givetian–middle Fammenian and Early Carboniferous times. Compared with replacement dolomites, Cd2 cements yield lower δ18O values (−14·2 to −9·3‰ VPDB), lower δ13C values (−3·0 to −0·7‰ VPDB), higher 87Sr/86Sr ratios (≈ 0·7100) and higher Th values (171–209 °C), which correspond to trapping temperatures (Tr) between 260 and 300 °C after pressure corrections. These data suggest that the dolomite cements precipitated from higher temperature hydrothermal fluids, derived from underlying siliciclastic deposits, and were associated with more intense hydrothermal events during Permian–Early Triassic time, when the host dolostones were deeply buried. The petrographic similarities between some replacement dolomites and Cd2 dolomite cements and the partial overlap in 87Sr/86Sr and δ18O values suggest neomorphism of early formed replacement dolomites that were exposed to later dolomitizing fluids. However, the dolomitization was finally stopped through invasion of meteoric water as a result of basin uplift induced by the Indosinian Orogeny from the early Middle Triassic, as indicated by the decrease in salinities in the dolomite cements in veins (5·1–0·4 wt% NaCl equivalent). Calcite cements generally yield the lowest δ18O values (−18·5 to −14·3‰ VPDB), variable δ13C values (−11·3 to −1·2‰ VPDB) and high Th values (145–170 °C) and low salinities (0–0·2 wt% NaCl equivalent), indicating an origin of high-temperature, dilute fluids recharged by meteoric water in the course of basin uplift during the Indosinian Orogeny. Faults were probably important conduits that channelled dolomitizing fluids from the deeply buried siliciclastic sediments into the basal carbonates, leading to intense dolomitization (i.e. Rd3, Cd1 and Cd2).
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  • 3
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Rare earth elements (REE) were determined in fine, medium and coarse crystalline replacement dolomites, and for saddle dolomite cements from the Middle Devonian Presqu'ile barrier from Pine Point and the subsurface of the Northwest Territories and north-eastern British Columbia. REE patterns of the fine crystalline dolomite are similar to those of Middle Devonian limestones from the Presqu'ile barrier. Fine crystalline dolomite occurs in the back-barrier facies and may represent penecontemporaneous dolomitization at, or just below, the sea floor. Medium crystalline dolomite is widespread in the lower southern and lower central barrier. Medium crystalline dolomite is slightly depleted in heavy REE compared with Devonian marine limestones and fine crystalline dolomite, and has negative Ce and Eu anomalies. Medium crystalline dolomites replaced pre-existing limestones or were recrystallized from earlier fine crystalline dolomites. During these processes, the REE patterns of their precursors were modified. Late stage, coarse crystalline replacement dolomite and saddle dolomite cements occur together in the upper barrier and have similar geochemical signatures. Coarse crystalline dolomites have negative Eu anomalies, and those from the Pine Point area also have positive La anomalies. Saddle dolomites are enriched in light REE and have positive La anomalies. The REE patterns of coarse crystalline dolomite and saddle dolomite differ from those of marine limestones and fine and medium crystalline dolomites, suggesting that different diagenetic fluids were responsible for these later dolomites.Although massive dolomitization requires relatively large volumes of fluids in order to provide the necessary amounts of Mg2-. dolomitization and subsequent recrystallization may not necessarily modify the REE signatures of the precursor limestones because of the low concentrations of REE in most natural fluids. Thus, relative fluid-rock ratios during diagenesis may be estimated from REE patterns in the diagenetic and precursor minerals. Fine crystalline dolomites retain the REE patterns of their limestone precursors. In the medium and coarse crystalline dolomites the precursor REE patterns were apparently altered by large volumes of fluids involved during dolomitization. This study suggests that REE compositions of dolomites and their limestone precursors may provide important information about the relative amounts of fluids involved during diagenetic processes, such as dolomitization.
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  • 4
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Peritidal carbonates of the Lower Jurassic (Liassic) Gibraltar Limestone Formation, which form the main mass of the Rock of Gibraltar, are replaced by fine and medium crystalline dolomites. Replacement occurs as massive bedded or laminated dolomites in the lower 100 m of an ≈460-m-thick platform succession. The fine crystalline dolomite has δ18Ο values either similar to, or slightly higher than, those expected from Early Jurassic marine dolomite, and δ13C values together with 87Sr/86Sr ratios that overlap with sea-water values for that time, indicating that the dolomitizing fluid was Early Jurassic sea water. Absence of massive evaporitic minerals and/or evaporite solution-collapse breccias in these carbonate rocks indicates that the salinity of sea water during dolomitization was below that of gypsum precipitation. The occurrence of peritidal facies, a restricted microbiota and rare gypsum pseudomorphs are also consistent with penesaline conditions (salinity 72–199‰). The medium crystalline dolomite has some δ18Ο and δ13C values and 87Sr/86Sr ratios similar to those of Early Jurassic marine dolomites, which indicates that ambient sea water was again a likely dolomitizing fluid. However, the spread of δ18Ο, δ13C and 87Sr/86Sr values indicates that dolomitization occurred at slightly increased temperatures as a result of shallow (≈500 m) burial or that dolomitization was multistage. These data support the hypothesis that penesaline sea water can produce massive dolomitization in thick peritidal carbonates in the absence of evaporite precipitation. Taking earlier models into consideration, it appears that replacement dolomites can be produced by sea water or modified sea water with a wide range of salinities (normal, penesaline to hypersaline), provided that there is a driving mechanism for fluid migration. The Gibraltar dolomites confirm other reports of significant Early Jurassic dolomitization in the western Tethys carbonate platforms.
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  • 5
    Publication Date: 2004-06-01
    Print ISSN: 0037-0738
    Electronic ISSN: 1879-0968
    Topics: Geosciences
    Published by Elsevier
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  • 6
    Publication Date: 1994-10-01
    Print ISSN: 0016-7037
    Electronic ISSN: 1872-9533
    Topics: Chemistry and Pharmacology , Geosciences
    Published by Elsevier
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  • 7
    Publication Date: 2003-11-01
    Description: The Upper Ordovician Midale field is located in the northern Williston basin in southeast Saskatchewan, Canada. Hydrocarbons are hosted mainly in the dolomite reservoirs with burrowed textures in the upper Yeoman Formation. These reservoirs are characterized by intercrystalline porosity in the dolomitized matrix, with variable amounts of vugs and fractures, and can be divided into four zones. Reservoir zones 1 and 2, typically 6–10 m (20–33 ft) thick in total, are situated in the upper part of the traps and commonly bear oil. Although the underlying zones 3 and 4 are thicker, they commonly contain only water because they are located below the spillpoint of the hydrocarbon traps. The seismic reflection of the Red River reservoirs in the Midale field is characterized by a weak- to medium-amplitude trough immediately above the positive reflection of the Winnipeg shale. Where all four zones are present, an additional peak occurs on the seismic profile above the original reservoir reflection. This additional peak, however, disappears where reservoir zones 3 and 4 pinch out. Where there is an increase in the thickness of reservoir zones 1 and 2 or amalgamation of zone 1 with zone 2, the Red River reservoirs are characterized by high-amplitude and high-frequency reflections on seismic profiles. The Ordovician oil pools in the Midale area are associated with low-relief anticline structures. These low-relief structures are interpreted as the compactional drape of Red River strata over local Precambrian basement highs. The source of hydrocarbons in the Red River reservoirs is Ordovician kukersites. A wide range of API fractions for the oils from the Midale pools suggests a mixing of low-maturity oils, sourced from local kukersite beds, and high-maturity oils that migrated over a long distance from the south. The hydrocarbon production from Red River Midale pools is characterized by the fast rise of water cut and high water output, which can be attributed to the small pool size and the fracture systems connecting oil and water zones. Renhai Pu received a B.S. degree in petroleum geology from the Chengdu College of Geology (China) in 1983, an M.S. degree from the China University of Geosciences (Beijing) in 1990, and a Ph.D. from Northwest University (China) in 1998. He has been teaching seismic interpretation and sequence stratigraphy in Northwest University (China) for 13 years. His current research interests are in reservoir prediction and exploration of subtle traps.Hairuo Qing is an associate professor at the University of Regina. His research interests include characterization of carbonate reservoirs, geochemistry and diagenesis of dolomites, and secular variation of isotopic composition of seawater in geologic history. He obtained his B.Sc. degree from the Chengdu University of Technology and his M.Sc. degree and his Ph.D. (Dean's honor list) from McGill University. Don Kent is a professor emeritus and adjunct professor at the University of Regina, as well as a consulting petroleum geologist. His interests are carbonate sedimentology and diagenesis and carbonate reservoir characterization. He has spent 44 years studying and publishing papers on Paleozoic carbonates in the northern Williston basin, with particular emphasis on Mississippian, Devonian, and Ordovician rocks. Mark A. Urban received a B.Sc. degree in geology from the University of Regina in 2002. He is currently a graduate student at the same university, working on an M.Sc. project on reservoir characterization of the Red River “B” in the northern Williston basin.
    Print ISSN: 0149-1423
    Electronic ISSN: 1943-2674
    Topics: Geosciences
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  • 8
  • 9
    Publication Date: 2001-02-27
    Print ISSN: 0037-0746
    Electronic ISSN: 1365-3091
    Topics: Geosciences
    Published by Wiley
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  • 10
    Publication Date: 2004-10-01
    Print ISSN: 0037-0746
    Electronic ISSN: 1365-3091
    Topics: Geosciences
    Published by Wiley
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