Publication Date:
2011-01-01
Description:
A theory of square-wave voltammetry of two-step electrode reaction with kinetically controlled electron transfers is developed, and a special case of thermodynamically unstable intermediate is analyzed. If the first reaction step is reversible and the second one is quasireversible, the response splits into two peaks if the scan direction is inverted. The separation of these peaks increases with frequency.
Print ISSN:
2090-3529
Electronic ISSN:
2090-3537
Topics:
Chemistry and Pharmacology
,
Electrical Engineering, Measurement and Control Technology
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