ALBERT

Description: Understanding the mechanical behaviors of granite after thermal treatment under loading and unloading conditions is of utmost relevance to deep geothermal energy recovery. In the present study, a series of loading and unloading triaxial compression tests (20, 40 and 60 MPa) on granite specimens after exposure to different temperatures (20, 200, 300, 400, 500 and 600 °C) was carried out to quantify the combined effects of thermal treatment and loading/unloading stress conditions on granite strength and deformation. Changes in the microstructure of granite exposed to high temperatures were revealed by optical microscopy. The experimental results indicate that both, thermal treatment and loading/unloading stress conditions, degrade the mechanical behaviors and further decrease the carrying capacity of granite. The gradual degradation of the mechanical characteristics of granite after thermal treatment is mainly associated with the evolution of thermal micro-cracks based on optical microscopy observations. The unloading stress state induces the extension of tension cracks parallel to the axial direction, and thus, the mechanical properties are degraded. Temperatures above 400 °C have a more significant influence on the mechanical characteristics of granite than the unloading treatment, whereby 400 °C can be treated as a threshold temperature for the delineation of significant deterioration. This study is expected to support feasibility and risk assessments by means of providing data for analytical calculations and numerical simulations on granite exposed to high temperatures during geothermal energy extraction.

Description: Determining thin layer thickness is very important for reservoir characterization and CO2 quantification. Given its high time-frequency resolution and robustness, the complex spectral decomposition method was applied on time-lapse 3D seismic data from the Ketzin pilot site for CO2 storage to evaluate the frequency-dependent characteristics of thin layers at the injection level. Higher temporal resolution and more stratigraphic details are seen in the all-frequency and monochromatic reflectivity amplitude sections obtained by complex spectral decomposition compared to the stacked sections. The mapped geologic discontinuities within the reservoir are consistent with the preferred orientation of CO2 propagation. Tuning frequency mapping shows the thicknesses of the reservoir sandstone and gaseous CO2 is consistent with the measured thickness of the sandstone unit from well logging. An attempt to discriminate between pressure effects and CO2 saturation using the extracted tuning frequency indicates that CO2 saturation is the main contributor to the amplitude anomaly at the Ketzin site. On the basis of determined thickness of gaseous CO2 in the reservoir, quantitative analysis of the amount of CO2 was performed and shows a discrepancy between the injected and calculated CO2 mass. This may be explained by several uncertainties, like structural reservoir heterogeneity, a limited understanding of the complex subsurface conditions, error of determined tuning frequency, the presence of ambient noise and ongoing CO2 dissolution.

Description: Potash seams are a valuable resource containing several economically interesting, but also highly soluble minerals. In the presence of water, uncontrolled leaching can occur, endangering subsurface mining operations. In the present study, the influence of insoluble inclusions and intersecting layers on leaching zone evolution was examined by means of a reactive transport model. For that purpose, a scenario analysis was carried out, considering different rock distributions within a carnallite-bearing potash seam. The results show that reaction-dominated systems are not affected by heterogeneities at all, whereas transport-dominated systems exhibit a faster advance in homogeneous rock compositions. In return, the ratio of permeated rock in vertical direction is higher in heterogeneous systems. Literature data indicate that most natural potash systems are transport-dominated. Accordingly, insoluble inclusions and intersecting layers can usually be seen as beneficial with regard to reducing hazard potential as long as the mechanical stability of leaching zones is maintained. Thereby, the distribution of insoluble areas is of minor impact unless an inclined, intersecting layer occurs that accelerates leaching zone growth in one direction. Moreover, it is found that the saturation dependency of dissolution rates increases the growth rate in the long term, and therefore must be considered in risk assessments.

Description: The LArge-scale Reservoir Simulator (LARS) has been previously developed to study hydrate dissociation in hydrate-bearing systems under in-situ conditions. In the present study, a numerical framework of equations of state describing hydrate formation at equilibrium conditions has been elaborated and integrated with a numerical flow and transport simulator to investigate a multi-stage hydrate formation experiment undertaken in LARS. A verification of the implemented modeling framework has been carried out by benchmarking it against another established numerical code. Three-dimensional (3D) model calibration has been performed based on laboratory data available from temperature sensors, fluid sampling, and electrical resistivity tomography. The simulation results demonstrate that temperature profiles, spatial hydrate distribution, and bulk hydrate saturation are consistent with the observations. Furthermore, our numerical framework can be applied to calibrate geophysical measurements, optimize post-processing workflows for monitoring data, improve the design of hydrate formation experiments, and investigate the temporal evolution of sub-permafrost methane hydrate reservoirs.

Description: Quantifying impacts on the environment and human health is a critical requirement for geological subsurface utilisation projects. In practice, an easily accessible interface for operators and regulators is needed so that risks can be monitored, managed, and mitigated. The primary goal of this work was to create an environmental hazards quantification toolkit as part of a risk assessment for in-situ coal conversion at two European study areas: the Kardia lignite mine in Greece and the Máza-Váralja hard coal deposit in Hungary, with complex geological settings. A substantial rock volume is extracted during this operation, and a contaminant pool is potentially left behind, which may put the freshwater aquifers and existing infrastructure at the surface at risk. The data-driven, predictive tool is outlined exemplary in this paper for the Kardia contaminant transport model. Three input parameters were varied in a previous scenario analysis: the hydraulic conductivity, as well as the solute dispersivity and retardation coefficient. Numerical models are computationally intensive, so the number of simulations that can be performed for scenario analyses is limited. The presented approach overcomes these limitations by instead using surrogate models to determine the probability and severity of each hazard. Different surrogates based on look-up tables or machine learning algorithms were tested for their simplicity, goodness of fit, and efficiency. The best performing surrogate was then used to develop an interactive dashboard for visualising the hazard probability distributions. The machine learning surrogates performed best on the data with coefficients of determination R2〉0.98, and were able to make the predictions quasi-instantaneously. The retardation coefficient was identified as the most influential parameter, which was also visualised using the toolkit dashboard. It showed that the median values for the contaminant concentrations in the nearby aquifer varied by five orders of magnitude depending on whether the lower or upper retardation range was chosen. The flexibility of this approach to update parameter uncertainties as needed can significantly increase the quality of predictions and the value of risk assessments. In principle, this newly developed tool can be used as a basis for similar hazard quantification activities.

Description: Intrusion of deep saline waters into freshwater aquifers does not only endanger the regional drinking water supply, but also rivers and stagnant waters and their fauna are threatened by salinisation. The upwelling of highly mineralised saline waters in large parts of the North German Basin is favoured by the presence of Elsterian glacial erosion windows in the Lower Oligocene Rupelian Clay, the most important hydraulic confining unit in this region. Lower precipitation rates and decreasing groundwater levels as a consequence of global climate change, but also anthropogenic interventions, such as increasing extraction rates or the use of the deep geologic subsurface as a reservoir, decrease the pressure potential in the freshwater column and may possibly accelerate this primarily geogenic salinisation process in the coming years. Density-driven flow and transport modelling was performed in the scope of the present study to investigate the upwelling mechanisms of deep saline waters across Quaternary window sediments in the Rupelian. Simulation results show that the interactions between the groundwater recharge rate and anthropogenic interventions such as extraction rates of drinking water wells or the utilisation of the deep subsurface, have a significant influence on the groundwater pressure potential in the freshwater aquifer and associated saltwater upwelling. In all scenarios, salinisation is most severe in the sediments of the erosion windows. Hydraulically conductive faults also intensify salinisation if located nearside erosion windows or induce a more distributed or localised salinisation in aquifers with drinking water relevance in areas that do not intersect with erosion windows. A decline in groundwater recharge thereby significantly favours upward saltwater migration. The simulation scenarios further show that a decrease in groundwater recharge also results in freshwater salinisation occurring up to 10 years earlier, which underlines the need for waterworks to initiate effective countermeasures quickly and in time.

Description: In the context of a potential utilisation of coal resources located in the Mecsek mountain area in Southern Hungary, an assessment of groundwater pollution resulting from a potential water-borne contaminant pool remaining in in situ coal conversion reactors after site abandonment has been undertaken in the scope of the present study. The respective contaminants may be of organic and inorganic nature. A sensitivity analysis was carried out by means of numerical simulations of fluid flow as well as contaminant and heat transport including retardation to assess spatial contaminant migration. Hereby, the main uncertainties, e.g., changes in hydraulic gradient and hydraulic contributions of the complex regional and local fault systems in the study area, were assessed in a deterministic way to identify the relevant parameters. Overall 512 simulations of potential groundwater contamination scenarios within a time horizon exceeding the local post-operational monitoring period were performed, based on maximum contaminant concentrations, cumulative mass balances as well as migration distances of the contaminant plume. The simulation results show that regional faults represent the main contaminant migration pathway, and that contamination is unlikely assuming the given reference model parametrisation. However, contamination within a simulation time of 50 years is possible for specific geological conditions, e.g., if the hydraulic conductivity of the regional faults exceeds a maximum value of 1 × 10−5 m s−1. Further, the parameter data analysis shows that freshwater aquifer contamination is highly non-linear and has a bimodal distribution. The bivariate correlation coefficient heatmap shows slightly positive correlations for the pressure difference, the fault permeability and the simulation time, as well as a negative correlation for the retardation coefficient. The results of this sensitivity analysis have been integrated into a specific toolkit for risk assessment for that purpose.

Description: Planned decommissioning of coal-fired plants in Europe requires innovative technical and economic strategies to support coal regions on their path towards a climate-resilient future. The repurposing of open pit mines into hybrid pumped hydro power storage (HPHS) of excess energy from the electric grid, and renewable sources will contribute to the EU Green Deal, increase the economic value, stabilize the regional job market and contribute to the EU energy supply security. This study aims to present a preliminary phase of a geospatial workflow used to evaluate land suitability by implementing a multi-criteria decision making (MCDM) technique with an advanced geographic information system (GIS) in the context of an interdisciplinary feasibility study on HPHS in the Kardia lignite open pit mine (Western Macedonia, Greece). The introduced geospatial analysis is based on the utilization of the constraints and ranking criteria within the boundaries of the abandoned mine regarding specific topographic and proximity criteria. The applied criteria were selected from the literature, while for their weights, the experts’ judgement was introduced by implementing the analytic hierarchy process (AHP), in the framework of the ATLANTIS research program. According to the results, seven regions were recognized as suitable, with a potential energy storage capacity from 1.09 to 5.16 GWh. Particularly, the present study’s results reveal that 9.27% (212,884 m2) of the area had a very low suitability, 15.83% (363,599 m2) had a low suitability, 23.99% (550,998 m2) had a moderate suitability, 24.99% (573,813 m2) had a high suitability, and 25.92% (595,125 m2) had a very high suitability for the construction of the upper reservoir. The proposed semi-automatic geospatial workflow introduces an innovative tool that can be applied to open pit mines globally to identify the optimum design for an HPHS system depending on the existing lower reservoir.

Description: This paper presents a series of surface experimental simulations of methane-oriented underground coal gasification using hydrogen as gasification medium. The main aim of the experiments conducted was to evaluate the feasibility of methane-rich gas production through the in situ coal hydrogasification process. Two multi-day trials were carried out using large scale gasification facilities designed for ex situ experimental simulations of the underground coal gasification (UCG) process. Two different coals were investigated: the “Six Feet” semi-anthracite (Wales) and the “Wesoła" hard coal (Poland). The coal samples were extracted directly from the respective coal seams in the form of large blocks. The gasification tests were conducted in the artificial coal seams (0.41 × 0.41 × 3.05 m) under two distinct pressure regimes - 20 and 40 bar. The series of experiments conducted demonstrated that the physicochemical properties of coal (coal rank) considerably affect the hydrogasification process. For both gasification pressures applied, gas from “Six Feet” semi-anthracite was characterized by a higher content of methane. The average CH4 concentration for “Six Feet” experiment during the H2 stage was 24.12% at 20 bar and 27.03% at 40 bar. During the hydrogasification of “Wesoła" coal, CH4 concentration was 19.28% and 21.71% at 20 and 40 bar, respectively. The process was characterized by high stability and reproducibility of conditions favorable for methane formation in the whole sequence of gasification cycles. Although the feasibility of methane-rich gas production by underground hydrogasification was initially demonstrated, further techno-economic studies are necessary to assess the economic feasibility of methane production using this process.

Description: The geothermal hot water reservoir below the small town of Waiwera in New Zealand has been known to the indigenous Māori for many centuries. Overproduction by European immigrants led to a water level decrease and consequently artesian flow from the wells and the seeps on the beach ceased. The Te Kaunihera o Tāmaki Makaurau Auckland Council established the Waiwera Thermal Groundwater Allocation and Management Plan to allow the geothermal system to recover. For a sustainable operation, the management regime can be informed by hydrogeological models based on monitoring data. The underlying geological model has been revised according to field observations and an existing numerical model transferred to the newly developed software package TRANSPORTSE. Monitoring and digitally derived data have been integrated in a geographic information system (GIS).