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  • 1
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    Carbon, nitrogen and sulphur of sediment core CRP-1 (Table 1) (1998)
    PANGAEA
    In:  Supplement to: Kettler, Richard M (1998): Preliminary results of bitumen and kerogen analyses of the CRP-1. Terra Antartica, 5(3), 669-672, hdl:10013/epic.28326.d001
    Details
    Publication Date: 2023-06-27
    Description: Sediments and rocks recovered in CRP-1 coring operations contain relatively little organic matter (average 0.4% TOC) and very small amounts of solvent-soluble organic matter ( average 60 µg bitumen/g rock). The kerogen recovered from these rocks has atomic H:C ratios that range from 0.7 to 1.0 and atomic O:C ratios that range from 0.14-0.22. This range of values could be produced by mixing coal detritus with aquatic organic matter. Coal with the O:C ratios necessary to produce the kerogen present in the CRP-1 samples occurs in outcrops of the Permian Beacon Supergroup proximal to the drillsite.
    Keywords: 16 km ENE Cape Roberts; Cape Roberts Project; Carbon, organic, total; Carbon, organic, total, standard deviation; Carbon, total; Carbon, total, standard deviation; Core wireline system; CRP; CRP-1; CWS; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Element analyser CNS, Carlo Erba NA1500; Nitrogen, standard deviation; Nitrogen, total; off Cape Roberts, Ross Sea, Antarctica; Sampling/drilling ice; Sulfur, standard deviation; Sulfur, total
    Type: Dataset
    Format: text/tab-separated-values, 250 data points
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  • 2
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    (Table 1) Geochemical analysis on sediment core CRP-3 (2001)
    PANGAEA
    In:  Supplement to: Kettler, Richard M (2001): Results of whole-rock organic geochemical analyses of the CRP-3 drillcore, Victoria Land Basin, Antarctica. Terra Antartica, 8(3), 303-308, hdl:10013/epic.28241.d001
    Details
    Publication Date: 2023-06-27
    Description: Sediments and rocks recovered in CRP-3 coring operations contain minute amounts of organic matter (average 0.3% TOC). TOC contents and C:N ratios are zoned systematically: those rocks encountered at depths greater than 330 meters below sea floor (mbsf) contain less organic matter and have higher TOC:N ratios (after correcting for inorganic N) than do shallower rocks. The only two samples that have TOC values greater than 1% also contain abundant granule to silt-sized particles of coal. The total sulphur contents of these rocks is very low and indicates either that only small amounts of deposited organic matter were labile, or that no source of reactive iron was present during diagenesis.
    Keywords: Cape Roberts Project; Carbon, organic, total; Carbon, organic, total, standard deviation; Carbon, total; Carbon, total, standard deviation; Core wireline system; CRP; CRP-3; CWS; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Element analyser CHNS-O, Carlo Erba EA1108; Nitrogen, standard deviation; Nitrogen, total; Ross Sea; Sampling/drilling from ice; Sulfur, standard deviation; Sulfur, total
    Type: Dataset
    Format: text/tab-separated-values, 638 data points
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  • 3
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    Carbon and nitrogen of sediment core CRP-2A (Table 1)
    PANGAEA
    In:  Supplement to: Kettler, Richard M; Papastavros, E (2000): Preliminary results of bitumen and whole-rock elemental analyses of CRP-2/2A, Victoria Land Basin, Antarctica. Terra Antartica, 7(3), 361-367, hdl:10013/epic.28269.d001
    Details
    Publication Date: 2023-06-27
    Description: Sediments and rocks recovered in CRP-2/2A coring operations contain relatively little organic matter (average TOC=0.28%) and very small amounts of solvent-soluble organic matter. Because Early Oligocene sediment included significant amounts of coal detritus, TOC values are higher in Early Oligocene rocks than in younger rocks. TOC values are highest in the fine-grained rocks deposited as part of the highstand systems tract (HST) and TOC values decrease from the bottom to the top of the HST. The TOC:TN ratios observed in the CRP-2/2A core typically exceed 10, and are strong evidence that the preserved organic matter comprises a mixture of detrital coal and aquatic organic matter. Solvent-soluble organic matter comprises autochthonous bitumen derived from aquatic organic matter, allochthonous bitumen derived from deeper sedimentary rocks, and recycled bitumen derived from coal detritus.
    Keywords: 14.2 km at 096° true from Cape Roberts; Cape Roberts Project; Carbon, organic, total; Carbon, organic, total, standard deviation; Carbon, total; Carbon, total, standard deviation; Core wireline system; CRP; CRP-2; CRP-2A; CWS; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Element analyser CNS, Carlo Erba NA1500; Nitrogen, standard deviation; Nitrogen, total; off Cape Roberts, Ross Sea, Antarctica; Sampling/drilling from ice
    Type: Dataset
    Format: text/tab-separated-values, 700 data points
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  • 4
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    Organic geochemistry of ODP Site 128-799 (Table 1) (1995)
    PANGAEA
    In:  Supplement to: Kettler, Richard M (1995): Incipient bitumen generation in Miocene siliceous sedimentary rocks from the Japan Sea. Organic Geochemistry, 23(7), 699-708, https://doi.org/10.1016/0146-6380(95)00032-A
    Details
    Publication Date: 2024-01-09
    Description: Samples of Quaternary through Miocene diatomaceous sediment and siliceous sedimentary rock from the Japan Sea (ODP Leg 128, Site 799) were examined to determine the origin of bitumen encountered during drilling, whether previously published studies using Rock-Eval pyrolysis have accurately assessed organic matter type and maturity, and if evidence exists to postulate the presence of a Kuroko-type massive sulfide deposit at depth or along depositional strike. Whole-rock total organic carbon:total nitrogen ratios have values ranging from 31 to 4. Elemental atomic H:C and O:C kerogen ratios decrease from ca 1.3 and 0.3, respectively, in Quaternary and Pliocene samples to 1.2 and 0.1, respectively, in samples obtained from the bottom of the hole. The bitumen ratio of these rocks increases from 50 mg bitumen/g OC at 700 mbsf to 150 mg bitumen/g at 1000 mbsf. The kerogen in these samples comprises a mixture of marine and terrigenous organic material that reaches the earliest stages of catagenesis in the bottom part of this hole. The bitumen is dominated by asphaltenes, resins and polar components. Because these compounds have very high boiling points, Rock-Eval pyrolysis does not assess the thermal maturity, or organic matter type accurately in the early stages of catagenesis. The bitumens have a very low thermal maturity and the observed degree of thermal alteration is consistent with the modern geothermal gradient in the Kita-Yamato trough.
    Keywords: 128-799A; 128-799B; Bitumen; Carbon, inorganic, total; Carbon, organic, total; Carbon, organic, total/Nitrogen, total ratio; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Event label; Fraction; Hydrogen/Carbon ratio; Japan Sea; Joides Resolution; Leg128; Ocean Drilling Program; Odd-even predominance index; ODP; Oxygen/Carbon ratio; Phytane/n-C18 ratio; Pristane/Phytane ratio; Sample code/label; Sulfur, total
    Type: Dataset
    Format: text/tab-separated-values, 246 data points
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    DATA PANGAEA
  • 5
    Electronic Resource
    Electronic Resource
    Deformation structures and an alteration zone linked to deposition of volcanogenic sulphate in an ancient playa (Oligocene of Nebraska, USA) (2005)
    Oxford, UK : Blackwell Science Ltd
    Sedimentology 52 (2005), S. 0 
    Details
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Historic, sulphur-rich volcanic eruptions have altered global climate for as much as five years, and much larger events are known from the geologic record. At Scotts Bluff, Nebraska, Early Oligocene strata of the lower Arikaree Group contain a tephra bed with abundant calcite pseudomorphs after gypsum. Previous work has shown sulphate from the pseudomorphs in this tephra bears a high 17O anomaly indicative of oxidation of sulphur gases by ozone or hydrogen peroxide in the atmosphere. Possible sources of the tephra were caldera eruptions at about 28 Ma in the San Juan volcanic field of south-western Colorado (∼500 km SW of the study site) and the eastern Great Basin (∼1000 km WSW). The present sedimentological study shows that tephra and volcanogenic sulphate were deposited and preserved within a small, surface-discharging playa that developed on the irregular upper surface of aeolian siltstones of the subjacent White River Group. Sulphate solutions (including perhaps sulphuric acid) percolated downward within the vadose zone, dissolving early formed smectite cement within underlying volcaniclastic sandstones, reddening these rocks along an irregular alteration front. Preserved fine-scale stratification within the sandstones precludes the possibility that reddening took place during pedogenesis. Displacive growth of gypsum at the playa centre folded tephra beds and forced tephra into underlying sandstones, forming elongate cones. The large mass fraction of gypsum (now replaced by calcite) in the playa sediments suggests a huge, long-distance delivery of sulphate aerosols. Some of the sulphate and tephra may have come from the same eruption, or the fine-grained tephra may simply have aided preservation of dry-fog sulphate derived from an unrelated, effusive eruption of lava.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1365-3091.2004.00689.x
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  • 6
    Electronic Resource
    Electronic Resource
    Dissociation quotients of oxalic acid in aqueous sodium chloride media to 175°C (1991)
    Springer
    Journal of solution chemistry 20 (1991), S. 905-927 
    Details
    ISSN: 1572-8927
    Keywords: Oxalic acid ; ethanedioic acid ; dissociation constants ; thermodynamics ; potentiometry ; ionic strength
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The first and second molal dissociation quotients of oxalic acid were measured potentiometrically in a concentration cell fitted with hydrogen electrodes. The emf of oxalic acid-bioxalate solutions was measured relative to an HCl standard solution from 25 to 125°C over 25o intervals at nine ionic strengths ranging from 0.1 to 5.0 molal (NaCl). The molal dissociation quotients and available literature data were treated in the all anionic form by a five-term equation that yielded the following thermodynamic quantities at infinite dilution and 25°C: logK1a=−1.277±0.010, ΔH 1a o =−4.1±1.1 kJ-mol−1, ΔS 1a o =38±4 J-K−1-mol−1, and ΔC p,1a o =−168±41 J-K−1-mol−1. Similar measurements of the bioxalate-oxalate system were made at 25o intervals from 0 to 175°C at seven ionic strengths from 0.1 to 5.0m. A similar regression of the experimentally-derived and published equilibrium quotients using a seven-term equation yielded the following values at infinite dilution and 25°C: logK2a=−4.275±0.006, ΔH 2a o =−6.8±0.5 kJ-mol−1, ΔS 2a o =−105±2 J-K−1-mol−1, and ΔC p,2a o =−261±12 J-K−1-mol−1.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01074952
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  • 7
    Electronic Resource
    Electronic Resource
    Dissociation quotient of benzoic acid in aqueous sodium chloride media to 250°C (1995)
    Springer
    Journal of solution chemistry 24 (1995), S. 385-407 
    Details
    ISSN: 1572-8927
    Keywords: Benzoic acid ; dissociation constant ; ionization constant ; potentiometry ; ionic strength ; temperature and pressure dependence ; thermodynamics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The dissociation quotient of benzoic acid was determined potentiometrically in a concentration cell fitted with hydrogen electrodes. The hydrogen ion molality of benzoic acid/benzoate solutions was measured relative to a standard aqueous HCl solution at seven temperatures from 5 to 250°C and at seven ionic strengths ranging from 0.1 to 5.0 molal (NaCl). The molal dissociation quotients and selected literature data were fitted in the isocoulombic (all anionic) form by a six-term equation. This treatment yielded the following thermodynamic quantities for the acid dissociation equilibrium at 25°C and 1 bar: logKa=−4.206±0.006, ΔH a o =0.3±0.3 kJ-mol−1, ΔS a o =−79.6±1.0 J-mol−1-K−1, and ΔC p;a o =−207±5 J-mol−1-K−1. A five-term equation derived to describe the dependence of the dissociation constant on solvent density is accurate to 250°C and 200 MPa.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01150876
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  • 8
    Electronic Resource
    Electronic Resource
    Dissociation quotients of malonic acid in aqueous sodium chloride media to 100°C (1992)
    Springer
    Journal of solution chemistry 21 (1992), S. 883-900 
    Details
    ISSN: 1572-8927
    Keywords: Malonic acid ; propanedioic acid ; dissociation constants ; thermodynamics ; potentiometry ; ionic strength
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The first and second molal dissociation quotients of malonic acid were measured potentiometrically in a concentration cell fitted with hydrogen electrodes. The hydrogen ion molality of malonic acid/bimalonate solutions was measured relative to a standard aqueous HCl solution from 0 to 100°C over 25° intervals at five ionic strengths ranging from 0.1 to 5.0 molal (NaCl). The molal dissociation quotients and available literature data were treated in the all anionic form by a seven-term equation. This treatment yielded the following thermodynamic quantities for the first acid dissociation equilibrium at 25°C: logK 1a =-2.852±0.003, ΔH 1a /o =0.1±0.3 kJ-mol−1, ΔS 1a o =−54.4±1.0 J-mol−1-K−1, and ΔC p,1a o =−185±20 J-mol−1-K−1. Measurements of the bimalonate/malonate system were made over the same intervals of temperature and ionic strength. A similar regression of the present and previously published equilibrium quotients using a seven-term equation yielded the following values for the second acid dissociation equilibrium at 25°C: logK2a=−5.697±0.001, ΔH 2a o =−5.13±0.11 kJ-mol−1, ΔS 2a o =−126.3±0.4 J-mol−1-K−1, and ΔC p,2a o =−250+10 J-mol−1-K−1.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00651513
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  • 9
    Electronic Resource
    Electronic Resource
    Cadmium Malonate Complexation in Aqueous Sodium Trifluoromethanesulfonate Media to 75°C; Including Dissociation Quotients of Malonic Acid (1998)
    Springer
    Journal of solution chemistry 27 (1998), S. 195-216 
    Details
    ISSN: 1572-8927
    Keywords: Malonic acid ; propanedioic acid ; dissociation constants ; cadmium ; complexation constants ; sodium trifluoromethanesulfonate ; potentiometry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The molal formation quotients for cadmium–malonate complexes were measured potentiometrically from 5 to 75°C, at ionic strengths of 0.1, 0.3, 0.6 and 1.0 molal in aqueous sodium trifluoromethanesulfonate (NaTr) media. In addition, the stepwise dissociation quotients for malonic acid were measured in the same medium from 5 to 100°C, at ionic strengths of 0.1, 0.3, 0.6, and 1.0 molal by the same method. The dissociation quotients for malonic acid were modeled as a function of temperature and ionic strength with empirical equations formulated such that the equilibrium constants at infinite dilution were consistent, within the error estimates, with the malonic acid dissociation constants obtained in NaCl media. The equilibrium constants calculated for the dissociation of malonic acid at 25°C and infinite dilution are log K 1a=-2.86 ± 0.01 and log K 2a=-5.71 ± 0.01. A single Cd–malonate species, CdCH2C2O4, was identified from the complexation study and the formation quotients for this species were also modeled as a function of temperature and ionic strength. Thermodynamic parameters obtained by differentiating the equation with respect to temperature for the formation of CdCH2C2O4 at 25°C and infinite dilution are: K = 3.45 ± 0.09, ΔS° = 7 ± 6 kJ-mol-1, ΔS° = 91 ± 22 J-K--mol-1, and ΔC p o =400±300 J­K-1­mol-1.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022638817245
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  • 10
    Electronic Resource
    Electronic Resource
    Dissociation quotients of succinic acid in aqueous sodium chloride media to 225°C (1995)
    Springer
    Journal of solution chemistry 24 (1995), S. 65-87 
    Details
    ISSN: 1572-8927
    Keywords: Succinic acid ; butanedioic acid ; dissociation constants ; thermodynamics ; potentiometry ; ionic strength
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The first and second molal dissociation quotients of succinic acid were measured potentiometrically with a hydrogen-electrode, concentration cell. These measurements were carried out from 0 to 225°C over 25° intervals at five ionic strengths ranging from 0.1 to 5.0 molal (NaCl). The dissociation quotients from this and two other studies were combined and treated with empirical equations to yield the following thermodynamic quantities for the first acid dissociation equilibrium at 25°C: log K1a=−4.210±0.003; ΔH 1a 0 =2.9±0.2 kJ-mol−1; ΔS 1a 0 =−71±1 J-mol−1-K−1; and ΔC p1a 0 =−98±3 J-mol−1-K−1; and for the second acid dissociation equilibrium at 25°C: log K2a=−5.638±0.001; ΔH 2a 0 = −0.5±0.1 kJ-mol−1; ΔS 2a 0 =−109.7±0.4 J-mol−1-K−1; and ΔC p2a 0 = −215±8 J-mol−1-K−1.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00973050
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