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  • 1
    Publication Date: 2023-06-20
    Description: Thirty Devonian-Carboniferous Boundary sections of the Rhenish Slate Mountains and adjacent subsurface areas are reviewed with respect to litho-, event, conodont, ammonoid, sequence, and chemostratigraphy. In the interval from the base of the uppermost Famennian (Wocklum Beds, Wocklumian) to the base of the middle Tournaisian (base Lower Alum Shale), 11 conodont and 16 ammonoid (sub)zones are distinguished. The terminology of the Hangenberg Crisis Interval is refined, with an overall regressive Crisis Prelude below the main Hangenberg Extinction, which defines the base of the transgressive Lower Crisis Interval (Hangenberg Black Shale). The glacigenic and regressive Middle Crisis Interval (Hangenberg Shale/Sandstone) is followed by the overall transgressive Upper Crisis Interval that can be subdivided into three parts (I to III) with the help of conodont stratigraphy (upper costatus-kockeli Interregnum = upper ckI, Protognathodus kockeli Zone, and lower part of Siphonodella (Eosiphonodella) sulcata s.l./Pr. kuehni Zone). Protognathodus kockeli includes currently a wide range of forms, which variabilities and precise ranges need to be established before a precise GSSP level should be selected. Returning to its original definition, the former Upper duplicata Zone is re-named as Siphonodella (S.) mehli Zone. It replaces the S. (S.) jii Zone, which is hampered by taxonomic complications. The S. (S.) quadruplicata Zone of Ji (1985) is hardly supported by Rhenish data. The entry of typical S. (S.) lobata (M1) characterises an upper subdivision (subzone) of the S. (S.) sandbergi Zone; the new S. (S.) lobata M2 enters much earlier within the S. (S.) mehli Zone. The ammonoid-defined base of the Wocklum-Stufe (Upper Devonian = UD VI) begins with the Linguaclymenia similis Zone (UD VI-A1). The oldest S. (Eosiphonodella) enter within the Muessenbiaergia bisulcata Zone (UD VI-A2). The traditional Parawocklumeria paradoxa Zone of Schindewolf (1937) is divided into successive P. paprothae (VI-C1), P. paradoxa (VI-C2), and Mayneoceras nucleus (VI-C3) Subzones. In the lower Tournaisian (Lower Carboniferous = LC I), the Gattendorfia subinvoluta Zone is subdivided into G. subinvoluta (LC I-A2) and “Eocanites” nodosus (LC I-A3) Subzones. The Paprothites dorsoplanus Zone (LC I-B) can be divided into Pap. dorsoplanus (LC I-B1) and Paragattendorfia sphaeroides (LC I-B2) Subzones. Potential subdivisions of the Pseudarietites westfalicus (LC I-C) and Parag. patens Zones (LC I-D) are less distinctive. The unfossiliferous or argillaceous upper part of the Hangenberg Limestone and the overlying Lower Alum Shale Event Interval remain regionally unzoned for ammonoids.
    Description: Westfälische Wilhelms-Universität Münster (1056)
    Keywords: ddc:560 ; Rhenish Massif ; Devonian-Carboniferous Boundary ; Lithostratigraphy ; Biostratigraphy ; Hangenberg Crisis ; Carbon isotopes
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2024-02-23
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉ABSTRACT〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The study examines bioclastic carbonate contourites that arise from the broad spectrum of bottom‐current related sedimentary processes ranging from deposition to erosion. The result of the intermittent accumulation of sediment are thin and condensed successions with abundant hiatuses. Such bottom‐current deposits are poorly known, since the broadly accepted contourite‐facies model, the bi‐gradational sequence, characterizes environments of contourite depositional systems as a continuous accretion of fine‐grained siliciclastic sediments. To increase current understanding of the carbonate facies within hiatal contourite records, the Eifelian–Frasnian of the Tafilalt Platform in Morocco was investigated. The succession is divided into five facies associations that are interpreted to reflect pelagic sedimentation and deposition from bottom currents on a contourite terrace, a gently inclined section of the upper slope of Gondwana shaped by a water‐mass interface. Contourite deposition was mainly controlled by oxic clear‐water currents (documented by moderately to completely bioturbated limestones with abundant hydrogenetic ferromanganese nodules, and low organic‐carbon contents), at times also by an anoxic water mass (featured by organic‐rich coquinas with absent to sparse bioturbation and predominantly syngenetic framboidal pyrites). Biostratigraphic data and the overall depositional architecture display palaeoceanographic hydrodynamic processes associated with a shifting water‐mass interface. The inner terrace was characterized by an alongslope contourite channel and a small mounded drift at its downslope margin. Energetic bottom currents furthermore caused abraded surfaces, i.e. plain areas of non‐deposition and localized erosion, and sandy condensation layers. The microfacies reflects repeated alternation between suspension deposition, winnowing of fines, bedload traction, dynamic sediment bypassing and reworking, together with concomitant seafloor cementation. Coquinas of mainly planktonic and nektonic organisms are identified as integral parts of bi‐gradational contourite sequences showing inverse and normal grading. Hiatal lag concentrations of carbonate intraclasts, ferromanganese nodules and conodonts often drape hardgrounds and erosional surfaces at the midpoint of these frequently incomplete sequences. This Devonian case provides the opportunity to investigate the spatial and temporal variability of the bed‐scale contourite sequence, also with regard to the drift‐scale depositional architecture. In addition, the identified high‐resolution record is a starting point for unravelling the pattern of oceanic circulation in the Devonian greenhouse world.〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.7 ; Anti‐Atlas ; bi‐gradational sequence ; bioclastic contourite ; carbonate contourite ; cephalopod limestone ; contourite channel ; contourite terrace
    Language: English
    Type: doc-type:article
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  • 3
    Publication Date: 2024-03-12
    Description: A total of 556 samples (3 cm average sample spacing) were collected from the 12 m long Winsenberg section in order to reconstruct a floating timescale using cyclostratigraphic methods and to investigate paleoclimatic dynamics using selected elemental ratios. Samples were measured as a powder covered with Chemplex film on a Bruker S1 Titan 800 portable XRF at the University of Münster with the following settings: 40 kV, 20 mA, no filters, 75 s. Spectra were deconvoluted in Bruker Artrax software, and linearly calibrated using a set of 10 sedimentary standards of known composition and 11 calcite-quart mixtures. The composition of these standards is also included. Selected elemental ratios were tuned via the methods described in the accompanying manuscript, and are included in this dataset as well.
    Keywords: Age, relative; Astrochronology; Carbon isotopes; Cyclostratigraphy; Devonian; Fieldwork; Frasnian-Famennian; Germany; HAND; Kellwasser Crisis; Portable X-Ray Fluorescence; Potassium oxide/Aluminium dioxide ratio; Rhenish Massif; Sampling by hand; TOC; Winsenberg; Winsenberg_2021; XRD
    Type: Dataset
    Format: text/tab-separated-values, 982 data points
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  • 4
    Publication Date: 2024-03-12
    Keywords: Age, relative; Astrochronology; Carbon isotopes; Cyclostratigraphy; Devonian; Fieldwork; Frasnian-Famennian; Germany; HAND; Kellwasser Crisis; Portable X-Ray Fluorescence; Rhenish Massif; Sampling by hand; Stratigraphic height; TOC; Winsenberg; Winsenberg_2021; XRD
    Type: Dataset
    Format: text/tab-separated-values, 36 data points
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  • 5
    Publication Date: 2024-03-12
    Description: 4 samples were analysed for their relative clay mineral content. Glass smear slides were prepared and measured on a Philips X'Pert Modular Powder Diffractometer at the University of Münster, equipped with a Cu anode (1.5405 Å) and operated with the following settings: 45 kV voltage, 40 mA current, 0.02°θ step size, 1 s per measurement step, 3-50°2θ measuring range, 30 runs per sample, and no sample rotation. Note that the data obtained via this analysis is not quantitative.
    Keywords: Astrochronology; Carbon isotopes; Cyclostratigraphy; Devonian; Fieldwork; Frasnian-Famennian; Germany; HAND; Kellwasser Crisis; Portable X-Ray Fluorescence; Rhenish Massif; Sampling by hand; TOC; Winsenberg; Winsenberg_2021; XRD
    Type: Dataset
    Format: application/zip, 387.7 kBytes
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  • 6
    Publication Date: 2024-03-12
    Description: A total of 34 samples (35 cm average sample spacing) were analysed for organic carbon d13C in order to identify the two characteristic positive excursions associated with the Lower and Upper Kellwasser Events. Measurements were carried out at the Analytical, Environmental and Geo-Chemistry Research Group (AMGC) of the Vrije Universiteit Brussel (Belgium). The samples were decarbonated with 10% HCl in two steps, rinsed with milliQ water, and dried in an oven at 50°C. Total organic carbon (TOC) contents and δ13Corg compositions were determined on a Euro EA 150 Elemental Analyzer (CHNS) - Euro Vector HT-PyrOH combustion system coupled to a Nu-Instruments Horizon 2 isotope ratio mass spectrometer.
    Keywords: Astrochronology; Carbon, organic, total; Carbon, organic, total, standard deviation; Carbon isotopes; Cyclostratigraphy; Date of determination; Devonian; Element analyser CHNS; Fieldwork; Frasnian-Famennian; Germany; HAND; Kellwasser Crisis; Portable X-Ray Fluorescence; Rhenish Massif; Sample ID; Sampling by hand; Stratigraphic height; TOC; Winsenberg; Winsenberg_2021; XRD
    Type: Dataset
    Format: text/tab-separated-values, 240 data points
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  • 7
    Publication Date: 2024-03-12
    Description: A total of 34 samples (35 cm average sample spacing) were analysed for organic carbon d13C in order to identify the two characteristic positive excursions associated with the Lower and Upper Kellwasser Events. Measurements were carried out at the Analytical, Environmental and Geo-Chemistry Research Group (AMGC) of the Vrije Universiteit Brussel (Belgium). The samples were decarbonated with 10% HCl in two steps, rinsed with milliQ water, and dried in an oven at 50°C. Total organic carbon (TOC) contents and δ13Corg compositions were determined on a Euro EA 150 Elemental Analyzer (CHNS) - Euro Vector HT-PyrOH combustion system coupled to a Nu-Instruments Horizon 2 isotope ratio mass spectrometer. The results were calibrated using two international standards, IAEA-C6 (sucrose: δ13C = -10.45‰) and IA-R068 (soy protein: δ13C = -25.22‰), together with reference material IVA33802151, which is calibrated against these international standards (organic-rich sediment: δ13C = -28.85‰). This calibration was verified with a further reference material, IVA33802153 (organic-rich soil: δ13C = -22.88‰).
    Keywords: Astrochronology; Carbon isotopes; Cyclostratigraphy; Date of determination; Devonian; Element analyser CHNS; Fieldwork; Frasnian-Famennian; Germany; HAND; Kellwasser Crisis; Portable X-Ray Fluorescence; Rhenish Massif; Sample ID; Sampling by hand; Stratigraphic height; TOC; Winsenberg; Winsenberg_2021; XRD; δ13C, organic carbon; δ13C, organic carbon, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 170 data points
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  • 8
    Publication Date: 2024-03-12
    Description: A total of 556 samples (3 cm average sample spacing) were collected from the 12 m long Winsenberg section in order to reconstruct a floating timescale using cyclostratigraphic methods and to investigate paleoclimatic dynamics using selected elemental ratios. Samples were measured as a powder covered with Chemplex film on a Bruker S1 Titan 800 portable XRF at the University of Münster with the following settings: 40 kV, 20 mA, no filters, 75 s. Spectra were deconvoluted in Bruker Artrax software, and linearly calibrated using a set of 10 sedimentary standards of known composition and 11 calcite-quart mixtures. The composition of these standards is also included. Selected elemental ratios were tuned via the methods described in the accompanying manuscript, and are included in this dataset as well.
    Keywords: Age, relative; Astrochronology; Carbon isotopes; Cyclostratigraphy; Devonian; Fieldwork; Frasnian-Famennian; Germany; HAND; Kellwasser Crisis; Portable X-Ray Fluorescence; Rhenish Massif; Sampling by hand; Silicon dioxid/Calcium oxide ratio; TOC; Winsenberg; Winsenberg_2021; XRD
    Type: Dataset
    Format: text/tab-separated-values, 1132 data points
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  • 9
    Publication Date: 2024-03-12
    Description: A total of 152 samples (8 cm average sample spacing) were analysed for carbonate d13C in order to identify the two characteristic positive excursions associated with the Lower and Upper Kellwasser Events. Measurements on powdered samples weighing 120-150 μg were carried out on a ThermoScientific Delta V Plus mass spectrometer at the University of Münster, using an in-house standard (Kabonat-1; δ13C = 1.46‰, δ18O = -1.19‰) for calibration and an external standard (NBS-19; δ13C = 1.95‰, δ18O = -2.20‰) for long-term performance monitoring.
    Keywords: Astrochronology; Carbon isotopes; Corrected; Cyclostratigraphy; Date of determination; Devonian; Fieldwork; Frasnian-Famennian; Germany; HAND; Kellwasser Crisis; Mass spectrometer, Thermo Fisher Scientific, Delta V plus; Portable X-Ray Fluorescence; Rhenish Massif; Sample ID; Sampling by hand; Stratigraphic height; TOC; Winsenberg; Winsenberg_2021; XRD; δ13C, carbonate; δ13C, carbonate, standard deviation; δ18O, carbonate; δ18O, carbonate, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 1976 data points
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  • 10
    Publication Date: 2024-03-12
    Description: A total of 556 samples (3 cm average sample spacing) were collected from the 12 m long Winsenberg section in order to reconstruct a floating timescale using cyclostratigraphic methods and to investigate paleoclimatic dynamics using selected elemental ratios. Samples were measured as a powder covered with Chemplex film on a Bruker S1 Titan 800 portable XRF at the University of Münster with the following settings: 40 kV, 20 mA, no filters, 75 s. Spectra were deconvoluted in Bruker Artrax software, and linearly calibrated using a set of 10 sedimentary standards of known composition and 11 calcite-quart mixtures. The composition of these standards is also included. Selected elemental ratios were tuned via the methods described in the accompanying manuscript, and are included in this dataset as well.
    Keywords: Age, relative; Astrochronology; Carbon isotopes; Cyclostratigraphy; Devonian; Fieldwork; Frasnian-Famennian; Germany; HAND; Kellwasser Crisis; Portable X-Ray Fluorescence; Rhenish Massif; Sampling by hand; Titanium dioxide/Aluminium oxide ratio; TOC; Winsenberg; Winsenberg_2021; XRD
    Type: Dataset
    Format: text/tab-separated-values, 1096 data points
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