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  • 1
    Publication Date: 2011-01-11
    Description: Our understanding of the global budget of atmospheric hydrogen (H2) contains large uncertainties. An atmospheric Bayesian inversion of H2 sources and sinks is presented for the period 1991–2004, based on a two networks of flask measurement stations. The types of fluxes and the spatial scales potentially resolvable by the inversion are first estimated from an analysis of the correlations of errors between the different processes and regions emitting or absorbing H2. Then, the estimated budget of H2 and its uncertainties is presented and discussed, for five groups of fluxes and three groups of large regions, in terms of mean fluxes, seasonal and interannual variations, and long-term trends. One main focus of the study is the improvement of the estimate of H2 soil uptake, which is the largest sink of H2. Various sensitivity tests are performed defining an ensemble of more than 20 inversions. We show that inferring a robust estimate of the H2 soil uptake requires to prescribe the prior magnitude of some other sources and sinks with a small uncertainty. Doing so an estimate of the H2 soil uptake of −62 ± 3 Tg y−1 is inferred for the period 1991–2004 (the uncertainty is the residual error after inversion). The inferred soil H2 sink presents a negative long-term trend that is qualitatively consistent with a bottom-up process-based model.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 2
    Publication Date: 2012-08-15
    Description: A simple process-based model for the consumption of atmospheric hydrogen (H2) has been developed. The model includes a description of diffusion and biological processes which together control H2 flux into the soil. The model was incorporated into the LPJ-WHyMe Dynamic Global Vegetation Model, and used to simulate H2 fluxes over the 1988–2006 period. The model results have been confronted with field and laboratory measurements. The model reproduces observed seasonal cycles of H2 uptake at different sites and shows a realistic sensitivity to changes in soil temperature and soil water content in comparisons with field and laboratory measurements. A recent study, based on 3D atmospheric model inversion, found an increase of the global H2 sink from soils, with a trend of −0.77 Tg a−2 for the 1992–2004 period (fluxes are negative as soils act as a sink for atmospheric H2). For the same period, however, our process-based model calculates a trend of only −0.04 Tg a−2. Even when forced with drastic changes in soil water content, soil temperature and snow cover depth, our model is unable to reproduce the trend found in the inversion-based study, questioning the realism of such a large trend.
    Print ISSN: 0886-6236
    Electronic ISSN: 1944-9224
    Topics: Biology , Chemistry and Pharmacology , Geography , Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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