ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
We have obtained substantial alignment of I2(X 1Σ+g;v‘=0;J‘=13,15) seeded in supersonic beams of light carrier gases. Laser-induced fluorescence and a variant of the magnetic precession technique were used to measure the ratio n⊥/n(parallel) of molecules with the rotational angular momentum vector J perpendicular to the beam axis z to those with J parallel (or antiparallel) to z. As the nozzle stagnation pressure P0 is increased, this ratio increases markedly, reaches a maximum, and then decreases steadily. At the maximum, n⊥/n(parallel)=1.6, 1.7, and 2.2, respectively, for He, D2, and H2 as the carrier gases; this occurs at different pressures of the order of 103 Torr for nozzle diameter d=50 μm and temperature T0=315 K and corresponds to nearly the same rotational temperatures of about 6–8 K. We compare the observed dependence of alignment on P0⋅d with a J-dependent model that invokes two mechanisms for alignment, macroscopic gas transport, and anisotropic rotational cooling. The transport processes involve reorientation of J and give rise to alignment with n⊥/n(parallel)〉1; this dominates the initial increase with P0⋅d up to the maxima. The anisotropic cooling processes do not in our model involve reorientation of J but are fostered by the anisotropy of the rotational relaxation cross section; the alignment arises from different Boltzmann weights for molecules with J⊥z and J(parallel)z due to their slightly different rotational temperatures (about 5%). At high P0⋅d the net alignment is dominated by the anisotropic cooling term. At the correspondingly low rotational temperatures, this term counteracts the effect of gaseous transport, so the net alignment can reverse. Indeed, at high P0⋅d we do observe n⊥/n(parallel)〈1. For a higher rotational state (J‘=39,41) we find lower alignment that peaks at a higher rotational temperature (about 27 K), as predicted by the model.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.458855
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